Anthracene-bridged diarylamine isomers with identical amine-amine distances: Syntheses, (spectro)electrochemistry and theoretical calculations

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成果类型：

期刊论文

作者：

Xu, Jingwen;Xiao, Wenbo;Xia, Yonglin;Ye, Lingyun;Luo, Yuanyang;...

通讯作者：

Ya-Ping Ou

作者机构：

[Ou, Ya-Ping; Xia, Yonglin; Ye, Lingyun; Xu, Jingwen; Xiao, Wenbo; Luo, Yuanyang] Hengyang Normal Univ, Coll Chem & Mat Sci, Hunan Prov Key Lab Funct Met Organ Cpds, Hengyang, Hunan, Peoples R China.

[Ou, Ya-Ping; Xia, Yonglin; Ye, Lingyun; Xu, Jingwen; Xiao, Wenbo; Luo, Yuanyang] Hengyang Normal Univ, Coll Hunan Prov, Key Lab Organometall New Mat, Hengyang, Hunan, Peoples R China.

[Ou, Ya-Ping; Xia, Yonglin; Ye, Lingyun; Xu, Jingwen; Xiao, Wenbo; Luo, Yuanyang] Hunan Engn Res Ctr Monitoring & Treatment Heavy Me, Hengyang, Hunan, Peoples R China.

[Ou, Ya-Ping] Hengyang Normal Univ, Coll Chem & Mat Sci, Hunan Prov Key Lab Funct Met Organ Cpds, Hengyang 421008, Hunan, Peoples R China.

通讯机构：

[Ya-Ping Ou] C

College of Chemistry and Material Science, Hunan Provincial Key Laboratory of Functional Metal-Organic Compounds, Hengyang Normal University, Hengyang, Hunan, P. R. China<&wdkj&>Key Laboratory of Organometallic New Materials (Hengyang Normal University), College of Hunan Province, Hengyang, Hunan, P. R. China<&wdkj&>Hunan Engineering Research Center for Monitoring and Treatment of Heavy Metals Pollution in the upper Reaches of Xiangjiang River, Hengyang, Hunan, P. R. China

语种：

英文

关键词：

Anthracene bridge;Diarylamine isomers;Electrochemistry;Spectroelectrochemistry;Theoretical calculations

期刊：

Molecular Crystals and Liquid Crystals

ISSN：

1542-1406

年：

2023

卷：

764

期：

页码：

103-114

DOI：

10.1080/15421406.2023.2204563

基金类别：

National Natural Science Foundation of China [21602049]; Natural Science Foundation of Hunan Province, China [2021JJ30058, 2017JJ3004]; Scientific Research Projects of Education Department of Hunan Province [21A0441]; Science and Technology Bureau of Hengyang, China [2019jh010912]; Support Plan for Talents in Hengyang Normal University; Aid Programs for Technology Innovative Team, Key Discipline in Education Department of Hunan Province and Functional Metal-Organic Compounds of Hunan Science and Technology Innovation Team

机构署名：

本校为第一机构

院系归属：

化学与材料科学学院

摘要：

Two athracene-bridged diarylamine isomers 1 and 2 were constructed and fully characterized. The electrochemical results showed that Delta E of compound 2 was significantly higher than that of 1, which indicated that the mixed-valence compound 2(+) had higher thermodynamic stability than 1(+). Spectroelectrochemistry reflected that the NIR absorption of 2(+) exhibited a significant blue shift compared with reported compound 1(+). The calculated electronic coupling constant and spin density distribution indicated that 2(+) had larger charge delocalization than 1(+) under the identical amine-amin...

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Anthracene-bridged diarylamine isomers with identical amine-amine distances: Syntheses, (spectro)electrochemistry and theoretical calculations

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