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Various dicarboxylates induced six Zn(II)/Cd(II) coordination polymers containing a new benzoimidazolyl terpyridine ligand: syntheses, structural diversity, luminescence and gas adsorption properties

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成果类型:
期刊论文
作者:
Wang, Zi-Lang;Liu, Xin-Yao;Yang, Rou;Fu, Wei -Wei;Xia, Yi;...
通讯作者:
Fu, WW
作者机构:
[Fu, Wei -Wei; Wu, Qiu-Hong; Luo, Fen; Liu, Xin-Yao; Xia, Yi; Wang, Zi-Lang; Yang, Rou; Liu, Yang; Fu, WW; Li, Xin-Yi; Chen, Man-Sheng] Key Lab Funct Met Organ Cpds, Hengyang 421008, Peoples R China.
[Fu, Wei -Wei; Wu, Qiu-Hong; Luo, Fen; Liu, Xin-Yao; Xia, Yi; Wang, Zi-Lang; Yang, Rou; Liu, Yang; Fu, WW; Li, Xin-Yi; Chen, Man-Sheng] Hengyang Normal Univ, Coll Hunan Prov, Key Lab Organometall New Mat, Hengyang 421008, Hunan, Peoples R China.
[Fu, Wei -Wei; Wu, Qiu-Hong; Luo, Fen; Liu, Xin-Yao; Xia, Yi; Wang, Zi-Lang; Yang, Rou; Liu, Yang; Fu, WW; Li, Xin-Yi; Chen, Man-Sheng] Hunan Prov Engn Res Ctr Monitoring & Treatment Hea, Hengyang 421008, Hunan, Peoples R China.
[Fu, Wei -Wei; Wu, Qiu-Hong; Luo, Fen; Liu, Xin-Yao; Xia, Yi; Wang, Zi-Lang; Yang, Rou; Liu, Yang; Fu, WW; Li, Xin-Yi; Chen, Man-Sheng] Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构:
[Fu, WW ] K
Key Lab Funct Met Organ Cpds, Hengyang 421008, Peoples R China.
Hengyang Normal Univ, Coll Hunan Prov, Key Lab Organometall New Mat, Hengyang 421008, Hunan, Peoples R China.
Hunan Prov Engn Res Ctr Monitoring & Treatment Hea, Hengyang 421008, Hunan, Peoples R China.
Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
语种:
英文
关键词:
Cadmium compounds;Carboxylation;Complex networks;Gas adsorption;Ligands;Single crystals;Topology;Zinc compounds;3D networks;Adsorption properties;Benzimidazoles;Complex 1;Coordination Polymers;Coordination-polymers;Dicarboxylates;Secondary building units;Structural diversity;Terpyridines;Luminescence
期刊:
Journal of Molecular Structure
ISSN:
0022-2860
年:
2024
卷:
1309
页码:
138196
基金类别:
We appreciate financial support from the Innovation Platform Open Fund Project of Hunan Provincial Education Department of China (No. 20K016) and the Scientific Research Project of Hengyang Normal University (2023HSKFJJ013). We are grateful to the useful comments of the editor and the reviewers.
机构署名:
本校为通讯机构
院系归属:
化学与材料科学学院
摘要:
Six Zn(II)/Cd(II) coordination polymers (CPs), namely, {[Zn2(bimphtpy)(p-bdc)1.5(OH)].(H2O)0.5}n (1), [Zn2(bimphtpy)2(tdc)2]n (2), {[Zn(bimphtpy)(cpoa)].4H2O}n (3), [Cd2(bimphtpy)(p-bdc)2(H2O)]n (4), {[Cd2(bimphtpy)(m-bdc)2(H2O)2].(H2O)0.75}n (5), and {[Cd(bimphtpy)(qda)].H2O}n (6), constructed from Nheterocyclic ligand 4'-(4-(benzimidazol-1-yl)phenyl)-4,2':6',4"-terpyridine (bimphtpy) and five dicarboxylic acids, (p-H2bdc = 1,4-benzenedicarboxylic acid, H2tdc = 2,5-thiophenedicarboxylic acid, H2cpoa =4-carboxyphenoxyacetatic acid, m-H2bdc = 1,3-benzenedicarboxylic acid, H2qda = hydroquinone-o...

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