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Sulfur Incorporation Using Disulfanes as the Sulfur Atom Source Enabled Metal‐Free Heteroannulation of 1,7‐Enynes

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成果类型:
期刊论文
作者:
Qin, Jing-Hao;Yu, Jiang-Xi;Li, Jin-Heng*;An, De-Lie*
通讯作者:
Li, Jin-Heng;An, De-Lie
作者机构:
[Qin, Jing-Hao; Li, Jin-Heng; An, De-Lie; Yu, Jiang-Xi] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
[Li, Jin-Heng; Yu, Jiang-Xi] Hengyang Normal Univ, Univ Hunan Prov, Key Lab Funct Met Organ Cpds Hunan Prov, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.
[Qin, Jing-Hao; Li, Jin-Heng; Yu, Jiang-Xi] Nanchang Hangkong Univ, Key Lab Jiangxi Prov Persistent Pollutants Contro, Nanchang 330063, Jiangxi, Peoples R China.
通讯机构:
[Li, JH; An, DL; Li, Jin-Heng] H
[Li, Jin-Heng] N
Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
Hengyang Normal Univ, Univ Hunan Prov, Key Lab Funct Met Organ Cpds Hunan Prov, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.
Nanchang Hangkong Univ, Key Lab Jiangxi Prov Persistent Pollutants Contro, Nanchang 330063, Jiangxi, Peoples R China.
语种:
英文
关键词:
enynes;disulfanes;heterocycles;oxidant;heteroannulation
期刊:
ADVANCED SYNTHESIS & CATALYSIS
ISSN:
1615-4150
年:
2019
卷:
361
期:
17
页码:
3974-3979
基金类别:
We thank the National Natural Science Foundation of China (Nos. 21625203 and 21871126) and the Jiangxi Province Science and Technology Project (Nos. 20171ACB20015 and 20165BCB18007) for financial support.
机构署名:
本校为通讯机构
院系归属:
化学与材料科学学院
摘要:
A new oxidative [2+2+1] heteroannulation of 1,7-enynes with disulfanes promoted by Et3N, producing 3,3a-dihydro-thieno[3,4-c]quinolin-4(5H)-ones, is described. This reaction is achieved by using equivalent amounts of 1,7-enynes, sulfur atoms (disulfanes), tert-butyl peroxybenzoate (TBPB) as an oxidant and Et3N as the base, and represents an unprecedented strategy to applications ...

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