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A carbon paste electrode modified with a cobalt(II) coordination polymer for the direct voltammetric determination of tryptophan

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成果类型:
期刊论文
作者:
Li, Wei*;Li, Changhong;Kuang, Yunfei;Deng, Peihong;Zhang, Shaohua;...
通讯作者:
Li, Wei
作者机构:
[Deng, Peihong; Zhang, Shaohua; Li, Wei; Xu, Jinsheng; Kuang, Yunfei] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
[Li, Changhong] Hunan Inst Technol, Dept Mat & Chem Engn, Hengyang 421002, Peoples R China.
通讯机构:
[Li, Wei] H
Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
Cobalt(II) coordination polymer;Carbon paste electrode;Tryptophan;Determination
期刊:
Microchimica Acta
ISSN:
0026-3672
年:
2012
卷:
176
期:
3-4
页码:
455-461
基金类别:
Hunan Provincial Natural Science Foundation of ChinaNatural Science Foundation of Hunan Province [11JJ9006, 10JJ3024]; Science and Technology Committee of Hunan Province [2009FJ3101, 2011FJ3037]; Science and Technology Committee of Hengyang [2011kj25]; Construct Program of the Key Discipline in Hunan Province
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
We have synthesized a cobalt(II) coordination polymer and have characterized it by various methods including X-ray single crystal structural analysis. The polymer was used as modifier to fabricate a carbon paste electrode that displays electrochemical activity towards tryptophan (Trp). Trp is oxidized at the surface of the electrode in buffer solution of pH 4.2, yielding a single peak at 814 mV. The experimental conditions such as the concentration, the composition and the pH values of the supporting electrolyte, accumulation time, and the scan...

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