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Syntheses, crystal structures and biological activity of the dialkytin complexes based on 2-oxo-3-phenylpropionic acid salicyloylhydrazone

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成果类型:
期刊论文
作者:
Tan, Yuxing;Zhang, Zhijian;Tan, Yuhuan;Kuang, Daizhi;Yu, Jiangxi;...
通讯作者:
Jiang, Wujiu
作者机构:
[Jiang, Wujiu; Tan, Yuxing; Yu, Jiangxi; Zhu, Xiaoming; Zhang, Zhijian; Kuang, Daizhi] Hengyang Normal Univ, Coll Hunan Prov, Key Lab Funct Organometall Mat, Hengyang, Peoples R China.
[Jiang, Wujiu; Tan, Yuxing; Yu, Jiangxi; Zhu, Xiaoming; Zhang, Zhijian; Kuang, Daizhi] Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang, Peoples R China.
[Tan, Yuhuan] Hunan Univ Sci & Technol, Coll Chem & Chem Engn, Xiangtan, Peoples R China.
通讯机构:
[Jiang, Wujiu] H
Hengyang Normal Univ, Coll Hunan Prov, Key Lab Funct Organometall Mat, Hengyang, Peoples R China.
Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang, Peoples R China.
语种:
英文
关键词:
Organotin;hydrazone;synthesis;crystal structure;biological activity
期刊:
Journal of Coordination Chemistry
ISSN:
0095-8972
年:
2017
卷:
70
期:
15
页码:
2606-2624
基金类别:
The Open Fund Project of Key Laboratory of Functional Organometallic Materials of Hengyang Normal University#&#&#GN16k01#&#&#GN16K03 Hunan Provincial Natural Science Foundation of China#&#&#2016JJ4008#&#&#2017JJ3003
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
Three new dialkytin complexes, {[o-OH–C6H4(O)C=N–N=C(CH2Ph)COO](n-Bu2Sn)}n (1), {[o-OH–C6H4(O)C=N–N=C(CH2Ph)COO](MeOH)(p-MeC6H5CH2)2Sn}2 (2), and {[o-OH–C6H4(O)C=N–N=C(CH2Ph)COO](EtOH)(C6H5CH2)2Sn}2 (3), were synthesized by reactions of 2-oxo-3-phenylpropionic acid salicyloylhydrazone with the corresponding diorganotin(IV) complex, respectively. All the complexes were characterized by IR, 1H, 13C, 119Sn NMR spectra, elemental analysis, X-ray single crystal diffraction and TGA. For in vitro antitumor activities, complexes were evaluated by...

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