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Syntheses, crystal structures and luminescent properties of Ag(I) complexes with benzilic carboxylate and 2,6-pyridinedicarboxylate

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成果类型:
期刊论文
作者:
Fu, Wei-Wei*;Xu, Liu;Zhang, Yan-Hua;Chen, Man-Sheng
通讯作者:
Fu, Wei-Wei
作者机构:
[Xu, Liu; Fu, Wei-Wei; Zhang, Yan-Hua; Chen, Man-Sheng] Hengyang Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Organometall Mat Hunan Prov Coll, Hengyang 421008, Hunan, Peoples R China.
通讯机构:
[Fu, Wei-Wei] H
Hengyang Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Organometall Mat Hunan Prov Coll, Hengyang 421008, Hunan, Peoples R China.
语种:
英文
关键词:
2,6-pyridinedicarboxylate;Benzilic carboxylate;Crystal structure;Luminescent property;Silver(I) complex
期刊:
Inorganic and Nano-Metal Chemistry
ISSN:
2470-1556
年:
2017
卷:
47
期:
8
页码:
1211-1215
基金类别:
Key Discipline Project of Hunan Province; Open Fund of Key Laboratory of Functional Organometallic Materials of Hunan Province College [GN14K02]; Aid program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
Two complexes [Ag(bpy)(H2O)](Hbac) (1) and [Ag-2(bpy)(2)(H2O)(2)](pdc)(H2O)(5) (2) (H(2)bac = benzilic acid, bpy = 4,4 '-bypyridine, H(2)pdc = 2,6-pyridinedicarboxylic acid) have been synthesized and characterized by IR, element analysis, X-ray-single crystal diffraction and TGA. Crystal data for 1: Monoclinic, space group C2/c, alpha = 18.8192(5) a, b = 12.7131(5) a, c = 17.8373(8) a, beta = 95.745(4), V = 4246.1(3) a(3) and Z = 8; 2: Triclinic, space group, P-1, alpha = 8.132(5) a, b = 10.485(6) a, c = 18.026(10) a, alpha = 96.194(10), beta = 91.047(11), gamma = 105.866(10), V = 1468.0(15) a...

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