Syntheses, Crystal Structures, and Magnetic Properties of Two Cobalt(II) Coordination Complexes with 4\'-Substituted 3,2\':6\',3\'\'-Terpyridine Ligands - 成果

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Syntheses, Crystal Structures, and Magnetic Properties of Two Cobalt(II) Coordination Complexes with 4'-Substituted 3,2':6',3''-Terpyridine Ligands

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成果类型：

期刊论文

作者：

Dong, Y. J.;Fu, W. W.;Gui, S. Y.;Liu, X.;Zi, L. L.;...

通讯作者：

W. W. Fu<&wdkj&>L. S. Wang

作者机构：

[Dong, Y. J.; Liu, X.; Wang, L. S.] Hubei Univ Technol, Sch Mat & Chem Engn, Collaborat Innovat Ctr Green Light Weight Mat & P, Hubei Prov Key Lab Green Mat Light Ind, Wuhan 430068, Peoples R China.

[Fu, W. W.; Zi, L. L.; Dong, Y. J.; Gui, S. Y.] Hengyang Normal Univ, Coll Chem & Mat Sci,Key Lab Funct Met Organ Cpds, Hunan Prov Engn Res Ctr Monitoring & Treatment He, Univ Hunan Prov,Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.

通讯机构：

[W. W. Fu] K

[L. S. Wang] H

Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional Organometallic Materials, University of Hunan Province, Hunan Provincial Engineering Research Center for Monitoring and Treatment of Heavy Metals Pollution in the Upper Reaches of Xiangjiang River, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang, P.R. China<&wdkj&>Hubei Provincial Key Laboratory of Green Materials for Light Industry, Collaborative Innovation Center of Green Light-Weight Materials and Processing, School of Material and Chemical Engineering, Hubei University of Technology, Wuhan, P.R. China

语种：

英文

关键词：

metal-organic frameworks;terpyridine;crystal structure;trimesic acid;magnetic property

期刊：

Russian Journal of Coordination Chemistry

ISSN：

1070-3284

年：

2022

卷：

期：

页码：

659-666

DOI：

10.1134/S1070328422100013

基金类别：

This work was supported by Open Research Foundation of Hubei Provincial Key Laboratory of Green Materials for Light Industry and Collaborative Innovation Center of Green Light-Weight Materials and Processing of Hubei University of Technology (no. 201611B16), the Scientific Research Fund of Hunan Provincial Education Department (no. 20K016), the Foundation of Key Laboratory of Functional Metal-Organic Compounds of Hunan Province (no. MO19K02), Youth Chutian Scholar Fund of Hubei Province (no. 4032401), State Key Laboratory of Structural Chemistry (no. 20180023), Hubei Provincial Key Laboratory of Green Materials for Light Industry (no. 201907A09).

机构署名：

本校为其他机构

院系归属：

化学与材料科学学院

摘要：

Two new cobalt(II) coordination complexes [Co(Phtpy)(HBTC)(0.5)](n)center dot nH(2)O (I) and [Co(Meophtpy)(HBTC)(0.5)](n)center dot nH(2)O (II) (Phtpy = 4'-(4-phenyl)-3,2':6',3''-terpyridine, Meophtpy = 4'-(4-methoxyphenyl)-3,2':6',3''-terpyridine,H3BTC = trimesic acid) were synthesized under solvothermal conditions. The structures of complexes I, II have been characterized by elemental analysis, FT-IR, TG analysis, PXRD and single crystal X-ray diffraction techniques (CCDC nos. 2123289 (I) and 2123290 (II)). For complex I, a two-dimensional (2D) layered structure is formed parallel to the bc ...

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