Mononuclear piano-stool iron 2-ethynylbenzo[b]thiophene complex: crystal structure and reversible oxidation studied by spectro-electrochemical and DFT methods

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成果类型：

期刊论文

作者：

Ou, Ya-Ping*;Zhang, Jing;Kuang, Daizhi;Zhang, Fuxing;Yu, Jiangxi;...

通讯作者：

Ou, Ya-Ping;Hartl, Frantisek

作者机构：

[Ou, Ya-Ping; Yu, Jiangxi; Zhu, Xiaoming; Zhang, Fuxing; Kuang, Daizhi] Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang, Peoples R China.

[Ou, Ya-Ping; Yu, Jiangxi; Zhu, Xiaoming; Zhang, Fuxing; Kuang, Daizhi] Hengyang Normal Univ, Coll Hunan Prov, Key Lab Funct Organometall Mat, Hengyang, Peoples R China.

[Zhang, Jing; Liu, Sheng Hua] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan, Peoples R China.

[Hartl, Frantisek] Univ Reading, Dept Chem, Reading, Berks, England.

通讯机构：

[Ou, Ya-Ping] H

[Hartl, Frantisek] U

Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang, Peoples R China.

Hengyang Normal Univ, Coll Hunan Prov, Key Lab Funct Organometall Mat, Hengyang, Peoples R China.

Univ Reading, Dept Chem, Reading, Berks, England.

语种：

英文

关键词：

Benzo[b]thiophene;X-ray crystallography;density functional theory;ethynylene linker;iron cyclopentadienyl complex;spectroelectrochemistry

期刊：

Journal of Coordination Chemistry

ISSN：

0095-8972

年：

2017

卷：

期：

页码：

722-733

DOI：

10.1080/00958972.2016.1278434

基金类别：

Opening Subjects of Hunan Province Key Laboratory of Functional Organometallic Materials [GN15K05]; Scientific Research Foundation of the Hengyang Normal University [14B23]

机构署名：

本校为第一且通讯机构

院系归属：

化学与材料科学学院

摘要：

A mononuclear iron complex with 2-ethynylbenzo[b]thiophene C-coordinated to the (η 5 -Cp*)(η 2 -dppe)Fe (Cp* = pentamethylcyclopentadienyl, dppe = 1,2-diphenylphosphinoethane) framework (1) was prepared and characterized by 1 H NMR, elemental analysis, and single crystal X-ray diffraction. The redox behavior of 1 was investigated by voltammetric methods and anodic spectroelectrochemistry in the UV–vis-NIR-IR region and compared with reference complexes including 2-ferrocenylbenzo[b]thiophene (2) and the 2-ethynylpyridine derivative of 1. The...

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Mononuclear piano-stool iron 2-ethynylbenzo[b]thiophene complex: crystal structure and reversible oxidation studied by spectro-electrochemical and DFT methods

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