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Organic-ion-intercalated FeSe-based superconductors

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成果类型:
期刊论文
作者:
Shi, M. Z.;Wang, N. Z.;Lei, B.;Shang, C.;Meng, F. B.;...
通讯作者:
Chen, X. H.
作者机构:
[Ma, L. K.; Chen, X. H.; Wang, N. Z.; Shi, M. Z.; Meng, F. B.; Lei, B.; Shang, C.] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China.
[Ma, L. K.; Chen, X. H.; Wang, N. Z.; Shi, M. Z.; Meng, F. B.; Lei, B.; Shang, C.] Univ Sci & Technol China, Dept Phys, Hefei 230026, Anhui, Peoples R China.
[Ma, L. K.; Chen, X. H.; Wang, N. Z.; Shi, M. Z.; Meng, F. B.; Lei, B.; Shang, C.] Univ Sci & Technol China, CAS Key Lab Strongly Coupled Quantum Matter Phys, Hefei 230026, Anhui, Peoples R China.
[Zhang, F. X.; Kuang, D. Z.] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
[Zhang, F. X.; Kuang, D. Z.] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
通讯机构:
[Chen, X. H.] U
[Chen, X. H.] N
Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China.
Univ Sci & Technol China, Dept Phys, Hefei 230026, Anhui, Peoples R China.
Univ Sci & Technol China, CAS Key Lab Strongly Coupled Quantum Matter Phys, Hefei 230026, Anhui, Peoples R China.
语种:
英文
期刊:
Physical Review Materials
ISSN:
2475-9953
年:
2018
卷:
2
期:
7
页码:
074801
基金类别:
National Key R&D Program of China [2017YFA0303001]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11534010, 91422303]; Hefei Science Center CAS [2016HSC-IU001]; "Strategic Priority Research Program (B)" of the Chinese Academy of SciencesChinese Academy of Sciences [XDB04040100]
机构署名:
本校为其他机构
院系归属:
化学与材料科学学院
摘要:
Finding a new derivative structure of FeSe-based superconductors with a high superconducting transition temperature ( Tc) is of great significance. Here, in this work, an organic-ion-[cetyltrimethyl ammonium ( CTA+)]-intercalated FeSe-based superconductor (CTA)0.3FeSe with Tc as high as 45 K is synthesized by an electrochemical intercalation method. The as-prepared (CTA)0.3FeSe has a hybrid crystal structure consisting of double layers of CTA+ and one layer of FeSe, which is consistent with a lateral-bilayer model. The superconductivity of (CTA...

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