期刊论文

Sun, Wei-Yin

英文

Inorganica Chimica Acta

0020-1693

2011

366

1

268-274

10.1016/j.ica.2010.11.019

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [20731004, 20721002]; National Basic Research Program of ChinaNational Basic Research Program of China [2007CB925103, 2010CB923303]; Grants-in-Aid for Scientific ResearchMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [20550063] Funding Source: KAKEN

本校为其他机构

Three new lanthanide-organic frameworks {[La(IP-py)(HIP-py)(H 2O)2]·H2O}n (1), {[Sm 2(IP-py)2(IP-pyH)2(H2O) 2]·12H2O}n (2) and {[Tb 3(IP-py)4(IP-pyH)(H2O)5] ·9H2O}n (3) have been prepared by reactions of the corresponding lanthanide salt with 5-(isonicotinamido)isophthalic acid (H 2IP-py). The complexes have been fully characterized by means of IR, elemental analyses and single-crystal X-ray diffraction. In compounds 1-3, the lanthanide centers are eight- and nine-coordinated with different coordination geometries and the carboxylate groups ...