期刊论文

Chen, Mansheng

英文

Transition Metal Chemistry

0340-4285

2012

37

5

463-468

10.1007/s11243-012-9610-7

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21003014]; Hunan Provincial Science and Technology Project [2010FJ3167]; Open Fund Project of Key Laboratories in Hunan Universities [11K009, 10K010]; Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science & Technology, P. R. China [2012CL07]

本校为第一且通讯机构

Reaction of FeSO4·7H2O with 5-(isonicotinamido) isophthalic acid (H2INAIP) in the presence of NaOH results in the formation of a two-dimensional network [Fe(INAIP)(H 2O)]n·2nH2O. In the complex, each INAIP2- ligand links three Fe(II) atoms to give a doublechain structure using its two carboxylate groups in μ1- η1:η1 and μ2-η1: η1 coordination modes. The chains are interlinked to form a layer structure through Fe-N interactions, which it is extended to a three-dimensional supramolecular structure by H-bonding interactions. The thermal and magnetic properties ...