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A graphene oxide-based electrochemical sensor for sensitive determination of 4-nitrophenol

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成果类型:
期刊论文
作者:
Li, Junhua*;Kuang, Daizhi;Feng, Yonglan;Zhang, Fuxing;Xu, Zhifeng;...
通讯作者:
Li, Junhua
作者机构:
[Liu, Mengqin; Xu, Zhifeng; Li, Junhua; Zhang, Fuxing; Feng, Yonglan; Kuang, Daizhi] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
[Liu, Mengqin; Xu, Zhifeng; Li, Junhua; Zhang, Fuxing; Feng, Yonglan; Kuang, Daizhi] Hengyang Normal Univ, Hunan Prov College, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
通讯机构:
[Li, Junhua] H
Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
语种:
英文
关键词:
4-Nitrophenol;4-nitrophenol (4-NP);Acetate buffers;Detection limits;Direct determination;Electrocatalytic activity;Electrochemical behaviors;ELectrochemical methods;Experimental parameters;Fabricated sensors;Glassy carbon electrodes;Heterogeneous rate constant;High selectivity;Long term stability;Optimal conditions;Overpotential;Quantitative detection;Reduction peak;Reduction peak currents;Scanning Electron Microscope;Sensitive detection;Signal-noise ratio;Transfer electrons;Water samples;Atomic force microscopy;Atomic spectroscopy;Electrochemical impedance spectroscopy;Glass membrane electrodes;Glassy carbon;Graphene;Optimization;Rate constants;Reduction;Scanning electron microscopy;Sensors;Electrochemical sensors;4 nitrophenol;acetic acid;carbon;graphene;graphene oxide;nanocoating;unclassified drug;catalysis;coating;detection method;electrochemical method;electrochemistry;electrode;electron;experimental study;noise;optimization;pH;phenolic compound;reaction kinetics;sensitivity analysis;sensor;article;atomic force microscopy;biosensor;chemical analysis;controlled study;electrochemical impedance spectroscopy;electrochemical sensor;electrochemistry;electron transport;film;microelectrode;molecular stability;nanofabrication;pH;reduction;scanning electron microscopy;Electrochemical Techniques;Electrodes;Environmental Monitoring;Graphite;Microscopy, Electron, Scanning;Nitrophenols;Sensitivity and Specificity;Spectroscopy, Fourier Transform Infrared;Water Pollutants, Chemical
期刊:
Journal of Hazardous Materials
ISSN:
0304-3894
年:
2012
卷:
201-202
页码:
250-259
基金类别:
This work is kindly supported by the supports of the Open Fund Project of Key Laboratory in Hunan Universities (nos. 09K099 , 10K010 ) and the Youth Backbone Teacher Training Program of Hengyang Normal University (2010) .
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
A graphene oxide (GO) film coated glassy carbon electrode (GCE) was fabricated for sensitive determination of 4-nitrophenol (4-NP). The GO-based sensor was characterized by scanning electron microscope, atomic force microscopy and electrochemical impedance spectroscopy. The electrochemical behaviors of 4-NP at the GO-film coated GCE were investigated in detail. In 0.1. M acetate buffer with a pH of 4.8, 4-NP yields a very sensitive and well-defined reduction peak at the GO-modified GCE. It is found that the GO film exhibits obvious electrocatal...

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