Abstract A new coordination polymer {[Eu2(Cl2C6H3OCH2COO)6(H2O)4]·(DMF)4·(H2O)2}n with 2,4‐dichlorophenoxy acetic acid as the ligand has been synthesized. The crystal data for this complex are as follows: monoclinic, space group P2(1)/n, a=0.86474(17) nm, b=3.2475(7) nm, c=1.3843(3) nm, β=92.81(3) °, V=3.8827(13) nm3, Dc=1.718 g/cm3, Z=2, µ(Mo Kα)=2.093 mm−1, F(000) =2008, final discrepancy factors R1=0.0454, wR2=0.1165. The crystal structure shows that the title complex forms one‐dimensional chain structure by bridging 2,4‐dichloroph...
