Catalytic Arylalkylation of Alkenyl Amines at Remote Sites via Directed Nickel Catalysis

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成果类型：

期刊论文

作者：

Han, Jian;Tang, Yinheng;Huang, Jie;Luo, Chun;Zhang, Lanlan;...

通讯作者：

Chao Wang

作者机构：

[Tang, Yinheng; Wang, Chao; Li, Wenyi; Han, Jian] Hengyang Normal Univ, Key Lab Funct Organometall Mat Hunan Prov Univ, Coll Chem & Mat Sci, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Hunan, Peoples R China.

[Zhang, Lanlan; Wang, Chao; Huang, Jie; Luo, Chun] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China.

[Han, Jian] Nanjing Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Adv Organ Mat, Nanjing 210023, Jiangsu, Peoples R China.

通讯机构：

[Chao Wang] C

College of Chemistry and Materials Science, Hengyang Normal University, Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional Organometallic Materials of Hunan Province Universities, Hengyang, Hunan, 421008 China<&wdkj&>Tianjin Key Laboratory of Structure and Performance for Functional Molecules

College of Chemistry, Tianjin Normal University, Tianjin, 300387 China

语种：

英文

关键词：

Nickel;Homogeneous catalysis;Arylalkylation;Amines;Picolinamide;Synthetic methodology;Boron

期刊：

中国化学

ISSN：

1001-604X

年：

2023

卷：

期：

页码：

631-636

DOI：

10.1002/cjoc.202200647

基金类别：

This work was supported by the National Natural Science Foundation of China (21901185, 22002037), the Innovation and Entrepreneurship Training Programme for University Students (202110546007), the Scientific Research Hunan Provincial Education Department (19A068) and funds provided by Tianjin Normal University.

机构署名：

本校为第一机构

院系归属：

化学与材料科学学院

摘要：

We disclose a Ni‐catalyzed remote arylalkylation of picolinamide tethered alkenyl amines with readily available aryl boronic acids and alkyl halides via six‐ or seven‐membered nickelacycles, providing a facile access to valuable δ,ε‐ and ε,ζ‐difunctionalized aliphatic amines. Comprehensive Summary Directing group‐assisted, transition metal‐catalyzed three‐component difunctionalization of alkenes has emerged as a powerful tool to drive molecular complexity. However, this strategy generally works with the substrates bearing directing ...

摘要(中文)：

Directing group-assisted, transition metal-catalyzed three-component difunctionalization of alkenes has emerge...展开更多 Directing group-assisted, transition metal-catalyzed three-component difunctionalization of alkenes has emerged as a powerful tool to drive molecular complexity. However, this strategy generally works with the substrates bearing directing groups in close proximity to the alkene moieties, due to the preference for formation of kinetically stable five-membered metallacycles. Herein, we have disclosed a complementary strategy t...

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Catalytic Arylalkylation of Alkenyl Amines at Remote Sites via Directed Nickel Catalysis

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