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Pt Nanoparticles Confined in a 3D Porous FeNC Matrix as Efficient Catalysts for Rechargeable Li-CO2/O2 Batteries

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成果类型:
期刊论文
作者:
Zhang, Peng-Fang;Zhuo, Hong-Ying;Dong, Yun-Yun;Zhou, Yao;Li, Yun-Wu;...
通讯作者:
Zhao, J.-S.;Li, Y.-W.;Wu, Y.-J.
作者机构:
[Hao, Hong-Guo; Shi, Wen-Jing; Xu, Shu-Ling; Zeng, Su-Yuan; Zhang, Peng-Fang; Kong, Xiang-Jin; Li, Da-Cheng; Li, Yun-Wu; Zhao, Jin-Sheng; Dong, Yun-Yun] Liaocheng Univ, Shandong Prov Key Lab Chem Energy Storage & Novel, Liaocheng 252000, Peoples R China.
[Hao, Hong-Guo; Shi, Wen-Jing; Xu, Shu-Ling; Zeng, Su-Yuan; Zhang, Peng-Fang; Kong, Xiang-Jin; Li, Da-Cheng; Li, Yun-Wu; Zhao, Jin-Sheng; Dong, Yun-Yun] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252000, Peoples R China.
[Zhuo, Hong-Ying] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China.
[Zhou, Yao; Li, Jun-Tao] Xiamen Univ, Coll Energy, Xiamen 361005, Peoples R China.
[Zhao, Shu] Beijing Univ Technol, Fac Mat & Mfg, Inst Adv Battery Mat & Devices, Beijing 100124, Peoples R China.
通讯机构:
[Yun-Wu Li; Jin-Sheng Zhao] S
[Yi-Jin Wu] K
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, and School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, P. R. China<&wdkj&>Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Hunan Province Universities Key Laboratory of Functional Organometallic Materials, College of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008, P. R. China
语种:
英文
关键词:
DFT calculations;Li-CO2/O2 battery;Pt/FeNC catalyst;in situ FTIR;porous FeNC matrix;size-confined
期刊:
ACS Applied Materials & Interfaces
ISSN:
1944-8244
年:
2023
卷:
15
期:
2
页码:
2940-2950
基金类别:
This work was supported by the National Natural Science Foundation of China (Nos. 22002055 and 21771095), the Natural Science Foundation of Shandong Province (ZR2021QB149 and ZR2021MB114), the PhD Initiation Program of Liaocheng University (318052013), and the PhD Initiation Program of Hengyang Normal University (2020QD06). The authors would like to thank Dr. Jin-Cheng Liu for his assistance in DFT analysis and Vei Wang’s team for developing the vaspkit.
机构署名:
本校为其他机构
院系归属:
化学与材料科学学院
摘要:
The cathodic product Li(2)CO(3), due to its high decomposition potential, has hindered the practical application of rechargeable Li-CO(2)/O(2) batteries. To overcome this bottleneck, a Pt/FeNC cathodic catalyst is fabricated by dispersing Pt nanoparticles (NPs) with a uniform size of 2.4 nm and 8.3 wt % loading amount into a porous microcube FeNC support for high-performance rechargeable Li-CO(2)/O(2) batteries. The FeNC matrix is composed of numerous two-dimensional (2D) carbon nanosheets, which is derived from an Fe-doping zinc metal-organic framework (Zn-MOF). Importantly, using Pt/FeNC as ...

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