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A promising sensing platform toward dopamine using MnO2 nanowires/electro-reduced graphene oxide composites

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成果类型:
期刊论文
作者:
He, Quanguo;Liu, Jun;Liu, Xiaopeng;Li, Guangli*;Chen, Dongchu;...
通讯作者:
Deng, Peihong;Li, Guangli
作者机构:
[He, Quanguo; Li, Guangli; Liang, Jing; Liu, Xiaopeng; Liu, Jun] Hunan Univ Technol, Coll Life Sci & Chem, Hunan Key Lab Biomed Nanomat & Devices, Zhuzhou 412007, Peoples R China.
[Chen, Dongchu] Foshan Univ, Sch Mat Sci & Energy Engn, Foshan 528000, Peoples R China.
[Deng, Peihong] Hengyang Normal Univ, Dept Chem & Mat Sci, 165 Huangbai Rd, Yanfeng Dist 421008, Hengyang, Peoples R China.
[Li, Guangli] Hunan Univ Technol, Coll Life Sci & Chem, 88 West Taishan Rd, Tianyuan Dist 412007, Zhuzhou, Peoples R China.
通讯机构:
[Deng, Peihong; Li, Guangli] H
Hengyang Normal Univ, Dept Chem & Mat Sci, 165 Huangbai Rd, Yanfeng Dist 421008, Hengyang, Peoples R China.
Hunan Univ Technol, Coll Life Sci & Chem, 88 West Taishan Rd, Tianyuan Dist 412007, Zhuzhou, Peoples R China.
语种:
英文
关键词:
MnO2 nanowires;Reduced graphene oxide;Modified electrode;Dopamine sensor;Electrocatalytic oxidation
期刊:
Electrochimica Acta
ISSN:
0013-4686
年:
2019
卷:
296
页码:
683-692
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [61703152]; Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2016JJ4010, 2018JJ3134]; Hengyang Normal University Provincial Platform Open Fund Project [GD16K02]; Fundamental Research Funds for the Central Universities of Central South University [2015zzts018]; Project of Science and Technology Plan in Zhuzhou [201707201806]; Opening Project of Key Discipline of Materials Science in Guangdong [CNXY2017001, CNXY2017002, CNXY2017003]
机构署名:
本校为通讯机构
院系归属:
化学与材料科学学院
摘要:
A promising sensing platform for the ultrasensitive detection of dopamine (DA) has been constructed using MnO2 nanowires-electrochemically reduced graphene oxide modified glassy carbon electrode (MnO2 NWs-ErGO/GCE). The proposed MnO2 NWs-ErGO/GCEs had the large electrochemical active area and relative low charge transfer resistant (R-ct). As a result, the response peak current of the MnO2 NWs-ErGO is about 13 times higher than that of the bare GCE, demonstrating the remarkable electrocatalytic activity toward DA. The electrochemical kinetics revealed that DA oxidation is quasi-reversible react...

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