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Selective separation of deltamethrin by molecularly imprinted polymers using a beta-cyclodextrin derivative as the functional monomer

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成果类型:
期刊论文
作者:
Xu, Zhi F.*;Wen, Ge;Kuang, Dai Z.;Zhang, Fu X.;Tang, Si P.
通讯作者:
Xu, Zhi F.
作者机构:
[Xu, Zhi F.; Tang, Si P.; Kuang, Dai Z.; Zhang, Fu X.] Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Coll Hunan Prov, Hengyang 421008, Peoples R China.
[Wen, Ge] Hengyang Chinese Med Corp Ltd, Unisplendour Guhan Grp, Hengyang, Peoples R China.
[Xu, Zhi F.] Hengyang Normal Univ, Dept Chem & Mat Sci, 165 Huangbai Rd, Hengyang 421008, Peoples R China.
通讯机构:
[Xu, Zhi F.] H
Hengyang Normal Univ, Dept Chem & Mat Sci, 165 Huangbai Rd, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
Deltamethrin;Molecular imprinting;Molecular recognition;Solid phase extraction;β-cyclodextrin
期刊:
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES
ISSN:
0360-1234
年:
2013
卷:
48
期:
5
页码:
336-343
基金类别:
Hunan Provincial Natural Science Foundation of ChinaNatural Science Foundation of Hunan Province [11JJ9005]
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
A deltamethrin-imprinted polymer (MIP1) was prepared using bis(-6-O-butanediacid monoester)-β-cyclodextrin (BBA-β-CD) as the functional monomer and toluene 2,4-diisocyanate (TDI) as the cross-linker. In comparison to the molecularly imprinted polymer where β-CD was applied as the functional monomer (MIP2), MIP1 showed a higher specific binding capacity (ΔCP) and an improved imprinting factor (IF) for deltamethrin. The selective recognition experiments demonstrated that compared to MIP2, MIP1 could better recognize its template over other substrates that had similar chemica...

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