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TWO Zn(II) AND Co(II) COORDINATION POLYMERS WITH 3-FOLD RIGHT-HANDED HELICAL CHAINS: SYNTHESES, STRUCTURAL CHARACTERIZATION, AND PHOTOLUMINESCENT PROPERTY

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成果类型:
期刊论文
作者:
Liu, Y.;Li, W.;Yang, Y-Q;Chen, M-S;Fu, W-W
通讯作者:
Y. Liu
作者机构:
[Yang, Y-Q; Li, W.; Chen, M-S; Fu, W-W; Liu, Y.] Hengyang Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang City, Peoples R China.
通讯机构:
[Y. Liu] K
Key Laboratory of Functional Organometallic Materials, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang City, People’s Republic of China
语种:
英文
关键词:
crystal structure;helical chain;photoluminescence;hydrogen bonding.
期刊:
Journal of Structural Chemistry
ISSN:
0022-4766
年:
2021
卷:
62
期:
5
页码:
740-747
基金类别:
This work has been funded by Aid programs for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province and the Key Discipline of Hunan Province and the Center for the Functionalization of Metal-Organic Frameworks Materials Studies.
机构署名:
本校为第一机构
院系归属:
化学与材料科学学院
摘要:
Two novel compounds [Zn(bitmb)(L)]center dot 2H(2)O and [Co(bitmb)(L)]center dot 2H(2)O are prepared under hydrothermal conditions (bitmb = 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene; H2L = 1,3-bis-(4-carboxy-phenoxy)propane) and characterized by the single crystal X-ray diffraction analysis. Both complexes are isostructural and contain 3-fold right-handed helical 1D chains. IR and PXRD spectra, TG curves,...

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