[唐文清; 张复兴] Department of Chemistry and Material Science, Hengyang Normal University, Key Laboratory of Functional Organometallic Materials, Hengyang, Hunan 421008, China
[龚道新] College of Resources and Environment, Hunan Agricultural University, Changsha, Hunan 410128, China
[Zeng R.-Y.] Department of Chemistry and Material Science, Hengyang Normal University, Key Laboratory of Functional Organometallic Materials, Hengyang, Hunan 421008, China, College of Resources and Environment, Hunan Agricultural University, Changsha, Hunan 410128, China
通讯机构:
[Tang, W.-Q.] D
Department of Chemistry and Material Science, Hengyang Normal University, Key Laboratory of Functional Organometallic Materials, China
Silicon-substituted carbonate hydroxylapatite (Si-CHAP) was successfully synthesized by hydrothermal method with abandoned eggshell as raw material, and characterized by FT-IR. Its adsorption equilibrium, kinetics and thermodynamics to Mn2+ were investigated under different temperatures. The results showed that the adsorption equilibrium well fitted to Langmuir equation, the maximum adsorption amount for Mn2+ onto Si-CHAP was 38.91 at 20, 41.49 at 30 and 43.10 mg/g at 40°C. The adsorption kinetics accorded with the pseudo second order kinetic ...