期刊论文

Xu, J.-S.

中文

过程工程学报

1009-606X

2014

14

4

677-682

(编号:2012FJ2002):湖南省科技计划重点资助项目 (编号:13K06):湖南省环保厅2013年环保科技项目:湖南省高校重点实验室开放基金资助

本校为第一且通讯机构

以正硅酸乙酯为硅源、三嵌段聚合物P123为模板剂,采用水热-后合成方法制备三胺基改性的多孔二氧化硅(3N-SBA-15)吸附剂,对其结构进行表征,并考察了吸附时间、体系初始pH值、吸附剂用量和温度等因素对水溶液中Cd~(2+)吸附的影响.结果表明,三胺基改性可显著增强SBA-15对Cd~(2+)的吸附能力,在pH=4.5、40℃、反应时间90 min的条件下,最大吸附容量为1.05 mmol/g. Langmuir方程可较好地描述Cd~(2+)在3N-SBA-15上的吸附平衡,20, 30和40℃下最大吸附容量分别为0.93, 0.97和1.05 mmol/g;热力学参数表明此吸附过程为自发吸热过程.对其吸附机理和材料的再生也进行了探索.

The triamino-modified porous SBA-15 (3N-SBA-15) adsorbent was prepared by posting-graft hydrothermal synthesis with Pluronic P123 as template agent and tetraethyl orthosilicate as the silicon source, and characterized. The effects of experimental conditions such as contact time, pH value, initial Cd 2+ concentration and temperature on the adsorption were studied. The adsorptive results showed that the adsorption equilibrium well fitted to Langmuir equation, the maximum adsorption capacity of Cd 2+ onto 3N-SBA-15 was 0.93 at 20℃, 0.97 at 30℃ a...