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The oxygen vacancy in Li-ion battery cathode materials

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成果类型:
期刊论文
作者:
Tang, Zhen-Kun;Xue, Yu-Feng;Teobaldi, Gilberto;Liu, Li-Min*
通讯作者:
Liu, Li-Min
作者机构:
[Tang, Zhen-Kun] Hengyang Normal Univ, Coll Phys & Elect Engn, Hengyang 421002, Peoples R China.
[Xue, Yu-Feng; Liu, Li-Min] Beihang Univ, Sch Phys, Beijing 100191, Peoples R China.
[Teobaldi, Gilberto] Sci & Technol Facil Council UKRI, Sci Comp Dept, Didcot OX11 0QX, Oxon, England.
[Teobaldi, Gilberto] Univ Liverpool, Stephenson Inst Renewable Energy, Dept Chem, Liverpool L69 3BX, Merseyside, England.
[Teobaldi, Gilberto] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England.
通讯机构:
[Liu, Li-Min] B
Beihang Univ, Sch Phys, Beijing 100191, Peoples R China.
语种:
英文
期刊:
Nanoscale Horizons
ISSN:
2055-6756
年:
2020
卷:
5
期:
11
页码:
1453-1466
基金类别:
Science Challenge Project [TZ2018004]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51602092, 11974037, 51861130360]; Science and Technology Innovation Project Foundation of Hunan Province [2018RS3103]; Hunan Provincial Natural Science Foundation of ChinaNatural Science Foundation of Hunan Province [2020JJ4147]; Research Foundation of Education Bureau of Hunan Province, China [19B076]; Royal Society Newton Advanced Fellowships; NAF [\R1\180242]
机构署名:
本校为第一机构
院系归属:
物理与电子工程学院
摘要:
The substantial capacity gap between available anode and cathode materials for commercial Li-ion batteries (LiBs) remains, as of today, an unsolved problem. Oxygen vacancies (OVs) can promote Li-ion diffusion, reduce the charge transfer resistance, and improve the capacity and rate performance of LiBs. However, OVs can also lead to accelerated degradation of the cathode material structure, and from there, of the battery performance. Understanding the role of OVs for the performance of layered lithium transition metal oxides holds great promise and potential for the development of next generati...

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