期刊论文

Jiang, Wu-Jiu;Tan, Yu-Xing

英文

Applied Organometallic Chemistry

0268-2605

2019

33

9

ARTN e5092

10.1002/aoc.5092

The project was supported by the Hunan Provincial Natural Science Foundation of China (No. 2017JJ3003), the Science and Technology Development Plan Project of Hengyang City (No. 2018KJ121), the Foundation of Key Laboratory of Functional Organometallic Materials, University of Hunan Province (No. GN19K07) and Hengyang Normal University discipline group construction project (No. 18XKQ01).

本校为第一且通讯机构

Eight disubstituted benzyltin complexes, i.e., {[R(O)C=N-N=C (Me)COO]R'2Sn(CH3OH)}n (1a and 2b), {[R(O)C=N-N=C (Me)COO]R'2Sn(CH3OH)}2 (1b and 1d) and {[R(O)C=N-N=C (Me)COO]R'2Sn}n (1c, 2a, 2c, and 2d) (R=C4H3O-, C4H3S-, p–t-Bu-C6H4- or p-MeO-C6H4-; R'=o-Cl-C6H4CH2- or o-Me-C6H4CH2-), were prepared from the reaction of arylformylhydrazine, pyruvic acid and disubstituted benzyltin dichloride with microwave irradiation. All complexes were characterized by FT-IR spectroscopy, 1H, 13C and 119Sn NMR spectroscopy, HRMS, elemental analysis, X-ray sing...