期刊论文

中文

衡阳师范学院学报

1673-0313

2017

03

65-70

10.13914/j.cnki.cn43-1453/z.2017.03.037

(16D06):the Doctoral Scientific Research Foundation of Hengyang Normal University (17A049,17C0226):Scientific Research Fund of Hunan Provincial Education Department of China (2015KG23):Key Project of Industrial Science and Technology Support of Hengyang City

本校为第一机构

在甲醇水混合溶剂中,以2,2'-联苯二甲酸,邻菲啰啉为配体与高氯酸锰合成了标题配合物Mn2(phen)6(ClO4)4.配合物(C30H24Cl2Mn N6O8.12,分子量为724.39),晶体属单斜晶系,空间群C2,晶胞参数:a =2.317 5(3) nm,b=1.464 98(17)) nm,c =2.172 2(4) nm,β=114.631 0°,V=6.703 9(16) nm3,Dc=1.435 g/cm3,Z=4,F(000)=2 960,μ=0.611 mm-1,.最终偏离因子R1 =0.076 2,wR2 =0.199 8.晶体结构表明:锰原子与3个邻菲啰啉的6个氮原子配位,形成六配位的变形四面体结构.对该配合物进行了量子化学计算.

The title complex has been synthesized with 2,2′-biphenyl dicarboxylic acid(H2L),2,2′-bipyridine (2,2′-bipy) and the manganese(II) perchlorate hexahydrate in the solvent mixture of water and methanol.It crystallizes (C30H24Cl2MnN6O8.12,Mr=724.39) in Monoclinic space group C2 with:a=2.317 5(3) nm,b=1.464 98(17)) nm,c =2.172 2(4) nm,β=114.631 0o,V=6.703 9(16) nm3,Dc=1.435 g/cm3,Z=4,F(000)=2 960,μ=0.611 mm-1,R1 =0.076 2,wR2 =0.199 8.The crystal structure shows that the manganese atom is coordinated with six nitrogen atoms from three 2,2′-bip...