作者机构：
Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, Hengyang, Hunan 421008, China
通讯机构：
Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, China
作者机构：
[Deng, Yi-Fang; Nie, Xue; Kuang, Dai-Zhi; Zhang, Chun-Hua] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构：
[Deng, Yi-Fang] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
摘要：
Article Crystal structure of catena-(μ3-pyrazine-2,3-dicarboxyato)-(2,2′- bipyridyl-& 2N,N′)cadmium(II) monohydrate, Cd(C6H2N2O4)(C10H8N2) · H2O was published on June 1, 2009 in the journal Zeitschrift für Kristallographie - New Crystal Structures (volume 224, issue 2).
摘要：
A one-dimensional chain coordination polymer [Co(II)(C_6H_5CH=CHCOOH)_2(4,4′- bipy)(H_2O)_5]n has been synthesized with cinnamylic acid, 4,4′-bipy and cobaltous chloride as raw materials. Crystal data for this complex: monoclinic, space group P21/c, a = 1.1481(3), b = 1.1230(2), c = 1.1759(3) nm, β = 97.054(4)o, V = 1.5046(6) nm~3, Mr= 617.50, Dc = 1.363 g/cm~3, Z = 2, μ(MoKα) = 0.627 mm~(-1), F(000) = 646, S = 1.062, R 0.0443 and wR = 0.1178. The crystal structure shows that two neighboring cobalt(II) ions are linked together by one 4,4′-bipy, and the whole complex molecule adopts a one-dimensional chain structure. Each cobalt(II) ion is coordinated with two nitrogen atoms from two 4,4′-bipy molecules and four oxygen atoms from four water molecules, giving a distorted octahedral coordination geometry. The electrochemical properties were analyzed by combining with the crystal structure.
