摘要：
A dinuclear cadmium complex [Cd_2(phen)_2(C_(14)H_(11)O_3)_4(CH_3CH_2OH)]·(CH_3OH)·(H_2O) has been synthesized with benzilic acid and 1, 10-phenanthroline by hydrothermal method. The crystal structure was determined by X-ray diffraction with crystal parameters as follows: triclinic system with space group Pi, a = 1.21298(10), b = 1.32586(11), c = 2.4815(2) nm, a = 76.2630(10), β = 81.4500(10), y = 69.1700(10)°, V= 3.6143(5) nm~3, Dc = 1.438 g/cm3, Z= 1, F(000) = 1600, the final GOOF = 0.937, R = 0.0521 and wR = 0.1328. In the title complex, the dinuclear structure is defined by carboxyl oxygen atoms adopting a monodentate bridged coordination mode. The coordination environment of Cd(II) ion is CdO_4N_2, giving a distorted octahedral coordination geometry. TG analysis shows that the title complex is stable under 140 ℃
作者机构：
Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Department of Chemistry and Materials Science, Hengyang 421008, China
通讯机构：
Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Department of Chemistry and Materials Science, China
摘要：
Article Crystal structure of triaqua- [bis(4-aminobenzenesulfonato-O)-bis(1,10-phenanthroline-k2N,N')praseodymìum(III) ] nitrate tetrahydrate, [Pr(H2O)3(C6H6O3NS)2(C12H8N2)2]NO3·4H2O was published on April 1, 2009 in the journal Zeitschrift für Kristallographie - New Crystal Structures (volume 224, issue 1-4).
作者：
Tan Xiong-Wen*;Li Chang-Hong;Li Dong-Ping;Li Wei;Yang Ying-Qun
期刊：
无机化学学报,2009年25(10):1877-1881 ISSN：1001-4861
通讯作者：
Tan Xiong-Wen
作者机构：
[Tan Xiong-Wen; Yang Ying-Qun; Li Wei] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.;[Li Chang-Hong] Hunan Inst Technol, Dept Mat & Chem Engn, Hengyang 421002, Hunan, Peoples R China.;[Li Dong-Ping] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China.
通讯机构：
[Tan Xiong-Wen] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
关键词：
苹果酸;晶体结构;钴(Ⅱ)配合物
摘要：
One dimensional chain cobalt coordination polymer has been synthesized with malic acid and cobalt (Ⅱ) chloride anhydrous,and characterized by the element analysis,IR,TGA and single crystal X-ray diffraction structure analysis.The title complex crystallizes in monoclinic system with space group P21,a=0.575 61(9) nm,b= 0.905 86(14) nm,c=0.841 02(13) nm,β=105.350(2)°;V=0.422 88(11) nm3,Z=2,Dc=1.924 Mg.m-3,μ=2.044 mm-1,F(000)=250,and final R1=0.029 3,wR2=0.074 2.The crystal structure shows that the ...更多cobalt ion is coordinated with four oxygen atoms from two different malate molecules and two oxygen atoms from two water molecules respectively,forming a distorted octahedral coordination geometry.Two adjacent cobalt (Ⅱ) atoms are bridged by one malate groups in bis-monodentate mode,constructing a one dimensional chain structure along b axis,with the adjacent Co …Co distance being 0.530 9 nm.Moreover,the molecules are packed in three-dimensional supramolecular network though the intermolecular hydrogen bonds.CCDC: 704441.
作者机构：
[Nie, Xue; Kuang, Dai-Zhi; Tan, Xiong-Wen; Zhang, Chun-Hua] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Coll Hunan Prov, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构：
[Zhang, Chun-Hua] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Coll Hunan Prov, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
摘要：
Article Crystal structure of triaqua-[bis(4-aminobenzenesulfonato-O)-bis(1,10- phenanthroline-κ 2N,N′)praseodymium(III)] nitrate tetrahydrate, [Pr(H2O)3(C6H6O3NS)2(C12H8N2)2]NO3 · 4H2O was published on June 1, 2009 in the journal Zeitschrift für Kristallographie - New Crystal Structures (volume 224, issue 2).
