摘要:
Two Cu(II) complexes [Cu(INAIP)(bbi)]·5H2O (1) and [Cu(INAIP)(phen)(H2O)]·H2O (2) were obtained by hydrothermal reactions of CuCl2·2H2O with 5-(isonicotinamido) isophthalic acid (H2INAIP) and N-donor ligands of 1,1′-(1,4-butanediyl)-bis(imidazole) (bbi) and 1,10-phenanthroline (phen), respectively. Both compounds crystallize in monoclinic space group C2/c. Single crystal X-ray diffraction analysis revealed that the bbi ligands connect [Cu(INAIP)] ID chains to form 2D bi-layers in complex 1, while complex 2 displays a ID chain structure, extending to 2D net through the π-π interactions. Complexes 1 and 2 are finally extended to 3D supramolecular structures by hydrogen bonding interactions. In addition, the magnetic property of complexes 1 and 2 has been investigated in the temperature range of 1.8~300 K, and the results show the weak antiferromagnetic interactions between the two Cu(II) ions bridged by carboxylate groups in 1, and the paramagnetic behavior of 2. CCDC: 781788,1; 781789, 2.
摘要:
Four new inorganic-organic hybrid frameworks [Mn(L)(H2O)(2)](n) (1), {[Co(L)(H2O)(3)]center dot 2H(2)O-CH3OH}(n) (2), {[Zn(L)(H2O)]center dot H2O) (3) and [Cd(HL)(2)](n) (4) [H2L = 4-(isonicotinamido)phthalic acid] have been synthesized and characterized by single-crystal X-ray diffraction analysis. Complex 1 has three-dimensional (3D) structure and topology related to SrAl2 (sra) with Schlafli symbol of (4(.)(2)6(3).8). And 2 displays (3,3)-connected two-dimensional (2D) network with (4.8(2)) topology, while 3 exhibits a uninodal (3,3)-connected (6,3) 2D network, which is further linked by N-H center dot center dot center dot O hydrogen bonding interactions to give 3D structure with hms topology and Schlafli symbol of (6(3))(6(9).8). Complex 4 with partial deprotonated HL- ligands also has a 2D network structure. In addition, the magnetic property of 1, nonlinear optical property of 3 and photoluminescence of 3 and 4 were investigated. (C) 2010 Elsevier Ltd. All rights reserved.
摘要:
The title compound, [Ag(L)]·H2O, 1, where HL=4-(isonicotinamido)benzoic acid, was synthesized in methanol solution and its crystal structure was determined by X-ray diffraction analysis. The crystal is of monoclinic, space group P21/c with a=0.571 8(8) nm, b=1.357 2(18) nm, c=1.558 0(2) nm, β=91.090(2)°, V=1.209 0(3) nm3, Z=4, Dc=2.009 g·cm-3, F(000)=722, Rint=0.042 9, R=0.027 1, wR=0.055 6. In complex 1, the Ag atoms are linearly coordinated by one O atom and one N atom of two ligand molecules. Each L-ligand in turn uses its one carboxylate group and one pyridinyl groups to connect two metal centers, then the one-dimensional (1D) chains is formed. On the other hand, the 1D chains are further connected by O1W-H1WB…O2 hydrogen bonds and Ag-O weak interactions to give a two-dimensional (2D) layer, finally, the 2D net extents to three-dimensional (3D) supramolecular framework by O1W-H1WB…O1 as well as N2-H2…O2 interactions.
作者机构:
[Deng, Yi-Fang; Kuang, Dai-Zhi; Chen, Man-Sheng; Zhang, Chun-Hua] Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
通讯机构:
[Kuang, Dai-Zhi] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
摘要:
The title compound, {[Cd(C19H13N4O 4)2(H2O)2]·4H 2O}n or {[Cd(BBA)2(H2O) 2]·4H2O}n, where BBA is 3,5-bis-(iso-nicotin-amido)-benzoate, is isotypic with its Mn isologue [Chen et al. (2009). J. Coord. Chem. 62, 2421-2428]. The cation sits on a twofold axis and is six-coordinated in a slightly distorted octa-hedral geometry; the polyhedra are linked into zigzag chains, which are further connected by N - H⋯O, O - H⋯O and O - H⋯N hydrogen bonds as well as π-π interactions [centroid-centroid distance of 3.639 (2) Å], giving a three-dimensional supra-molecular framework.
通讯机构:
[Tang, Si-Ping] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
摘要:
The title complex, [CuFe(C(5)H(5))(C(20)H(14)N(3))(C(12)H(8)N(2))](ClO(4))(2).C(2)H(3)N, consists of a mononuclear [Cu(C(12)H(8)N(2))(C(25)H(19)FeN(3))](2+) cation, two ClO(4) (-) anions (one of which is disordered over two positions with equal occupancy) and one CH(3)CN solvent mol-ecule. The Cu(II) center has a distorted square-pyramidal coordination with three N atoms of the 4'-ferrocenyl-2,2':6',2''- terpyridine (fctpy) ligand and one 1,10-phenanthroline (phen) N atom in the basal plane and a second phen N atom in the apical position with an axial distance of 2.254 (4) A. The disordered ClO(4) (-) anion is weakly coordin-ated to the Cu(II) ion with a Cu-O distance of 2.766 (11) A. The two cyclo-penta-dienyl rings of the ferrocenyl group are almost eclipsed with a deviation of 4.7 (1) degrees , and are involved in inter-molecular pi-pi inter-actions with the outer pyridyl rings of the fctpy ligands [centroid-centroid distance = 3.759 (2) A.].
作者机构:
Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, Hengyang, Hunan 421008, China
通讯机构:
Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, China
作者机构:
[Deng, Yi-Fang; Kuang, Dai-Zhi; Chen, Man-Sheng; Zhang, Chun-Hua] Hengyang Normal Univ, Key Lab Funct Organomet Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构:
[Chen, Man-Sheng] H;Hengyang Normal Univ, Key Lab Funct Organomet Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
摘要:
Article Crystal structure of aqua(2,2'-bipyridine-" 2N:N')(nitrato)-(4-aminobenzoato) cadmium(II) nitrate, [Cd(H2O)(NO3)(C10H8N2)(C7H7NO2)][NO3] was published on December 1, 2009 in the journal Zeitschrift für Kristallographie - New Crystal Structures (volume 224, issue 4).
通讯机构:
[Tang, Si-Ping] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
摘要:
In the title compound, C26H23N, the complete molecule is generated by crystallographic mirror symmetry, with the N atom and four C atoms lying on the reflection plane. The dihedral angles between the pyridine ring and pendant benzene rings are 2.9 (1), 14.1 (1) and 14.1 (1)°. Neighbouring mol-ecules are stabilized through inter-molecular π-π inter-actions along the c axis [centroid-to-centroid distance = 3.804 (2) Å], forming one-dimensional chains.
作者机构:
[Deng, Yi-Fang; Kuang, Dai-Zhi; Chen, Man-Sheng; Zhang, Chun-Hua] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构:
[Chen, Man-Sheng] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
摘要:
In the title linear coordination polymer, {[Cu(C2H 3O2)2(C12H10N 4)]·2H2O} n , the CuII atom is coordinated by two N atoms from two different symmetry-related 1,4-diimidazol-1-ylbenzene (dib) ligands and two carboxyl-ate O atoms from two acetate ligands in a square-planar geometry. The Cu atoms are linked by the dib ligands, forming an extended chain. These chains are linked by O- H⋯O hydrogen bonds into a three-dimensional supra-molecular network. The Cu II atom lies on a center of inversion.
作者机构:
[Deng Yi-Fang; Chen Man-Sheng; Kuang Dai-Zhi; Zhang Chun-Hua; Tang Si-Ping] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构:
[Zhang Chun-Hua] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
关键词:
锰配合物;晶体结构;6-二氯苯甲酸;水热合成
摘要:
A dinuclear manganese(II) complex, [Mn-2(L-1)(2)(phen)(4)]center dot(ClO4)(2) (1), has been synthesized and structurally characterized (HL1=2,6-dichlorobenzoic acid, phen=1,10-phenanthroline). It crystallizes in triclinic system, space group P1 with a=1.1123(4) nm, b=1.378 2(4) nm, c=2.085 7(3) nm, alpha=93.768(2)degrees, beta=90.606(10)degrees, gamma=95.606(3)degrees, V=3.174 8(15) nm(3), Z=2, C62H38Cl6Mn2N8O12, M-r=1 409.58, D-c=1.475 g.cm(-3), mu=0.718 mm(-1), F(000)=1 428, R= 0.064 3, wR =0.138 3. In the crystal the manganese atom is six-coordinated by two oxygen atoms from two different 2,6-dichlorobenzolate molecules and four nitrogen atoms from two 1,10-phenanthroline molecules, completing an octahedral geometry.
作者:
Deng Yi-Fang;Chen Man-Sheng;Kuang Dai-Zhi*;Zhang Chun-Hua;Tang Si-Ping
期刊:
无机化学学报,2008年24(9):1535-1538 ISSN:1001-4861
通讯作者:
Kuang Dai-Zhi
作者机构:
[Deng Yi-Fang; Chen Man-Sheng; Kuang Dai-Zhi; Zhang Chun-Hua; Tang Si-Ping] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构:
[Kuang Dai-Zhi] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
关键词:
锰配合物;晶体结构;5-二甲基苯甲酸;水热合成
摘要:
The title compound, [Mn3(L)6(CH3OH) 2]n·0.5nH2O (1), where HL=3,5-dimethylbenzoic acid, was synthesized and its crystal structure was determined by X-ray diffraction structure analysis. The crystal is of triclinic, space group P1 with a=1.275 1(13) nm, b=1.354 6(14) nm, c=1.882 3(19) nm, α=110.826(1)°, β=94.358(2)°, γ=108.038(1)°, V=2.825 4(5) nm3, Z=1, Mr=2 265.77, Dc=1.332 g·cm-3, μ=0.723 mm-1, F(000)=1 180, R int=0.037, R=0.056 4, wR=0.128 5. In the crystal the manganese atom is six-coordinated by six oxygen atoms, completing an octahedral geometry. The molecules are connected by 3,5-dimethylbenzoic acid to form a 1D chain structure bridged. CCDC: 694097.