作者机构：
[Deng, Yi-Fang; Kuang, Dai-Zhi; Chen, Man-Sheng; Zhang, Chun-Hua] Hengyang Normal Univ, Key Lab Funct Organomet Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Chen, Man-Sheng] H;Hengyang Normal Univ, Key Lab Funct Organomet Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
摘要：
Article Crystal structure of aqua(2,2'-bipyridine-" 2N:N')(nitrato)-(4-aminobenzoato) cadmium(II) nitrate, [Cd(H2O)(NO3)(C10H8N2)(C7H7NO2)][NO3] was published on December 1, 2009 in the journal Zeitschrift für Kristallographie - New Crystal Structures (volume 224, issue 4).
作者机构：
[Nie, Xue; Kuang, Dai-Zhi; Tan, Xiong-Wen; Zhang, Chun-Hua] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Coll Hunan Prov, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构：
[Zhang, Chun-Hua] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Coll Hunan Prov, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
摘要：
Article Crystal structure of triaqua-[bis(4-aminobenzenesulfonato-O)-bis(1,10- phenanthroline-κ 2N,N′)praseodymium(III)] nitrate tetrahydrate, [Pr(H2O)3(C6H6O3NS)2(C12H8N2)2]NO3 · 4H2O was published on June 1, 2009 in the journal Zeitschrift für Kristallographie - New Crystal Structures (volume 224, issue 2).
作者机构：
Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, Hengyang, Hunan 421008, China
通讯机构：
Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, China
作者机构：
[Deng, Yi-Fang; Kuang, Dai-Zhi; Chen, Man-Sheng; Zhang, Chun-Hua] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Chen, Man-Sheng] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
摘要：
In the title linear coordination polymer, {[Cu(C2H 3O2)2(C12H10N 4)]·2H2O} n , the CuII atom is coordinated by two N atoms from two different symmetry-related 1,4-diimidazol-1-ylbenzene (dib) ligands and two carboxyl-ate O atoms from two acetate ligands in a square-planar geometry. The Cu atoms are linked by the dib ligands, forming an extended chain. These chains are linked by O- H⋯O hydrogen bonds into a three-dimensional supra-molecular network. The Cu II atom lies on a center of inversion.
作者机构：
[Deng, Yi-Fang; Nie, Xue; Kuang, Dai-Zhi; Zhang, Chun-Hua] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构：
[Deng, Yi-Fang] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
摘要：
Article Crystal structure of catena-(μ3-pyrazine-2,3-dicarboxyato)-(2,2′- bipyridyl-& 2N,N′)cadmium(II) monohydrate, Cd(C6H2N2O4)(C10H8N2) · H2O was published on June 1, 2009 in the journal Zeitschrift für Kristallographie - New Crystal Structures (volume 224, issue 2).
作者机构：
[Deng Yi-Fang; Chen Man-Sheng; Kuang Dai-Zhi; Zhang Chun-Hua; Tang Si-Ping] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Zhang Chun-Hua] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
关键词：
锰配合物;晶体结构;6-二氯苯甲酸;水热合成
摘要：
A dinuclear manganese(II) complex, [Mn-2(L-1)(2)(phen)(4)]center dot(ClO4)(2) (1), has been synthesized and structurally characterized (HL1=2,6-dichlorobenzoic acid, phen=1,10-phenanthroline). It crystallizes in triclinic system, space group P1 with a=1.1123(4) nm, b=1.378 2(4) nm, c=2.085 7(3) nm, alpha=93.768(2)degrees, beta=90.606(10)degrees, gamma=95.606(3)degrees, V=3.174 8(15) nm(3), Z=2, C62H38Cl6Mn2N8O12, M-r=1 409.58, D-c=1.475 g.cm(-3), mu=0.718 mm(-1), F(000)=1 428, R= 0.064 3, wR =0.138 3. In the crystal the manganese atom is six-coordinated by two oxygen atoms from two different 2,6-dichlorobenzolate molecules and four nitrogen atoms from two 1,10-phenanthroline molecules, completing an octahedral geometry.
作者：
Deng Yi-Fang;Chen Man-Sheng;Kuang Dai-Zhi*;Zhang Chun-Hua;Tang Si-Ping
期刊：
无机化学学报,2008年24(9):1535-1538 ISSN：1001-4861
通讯作者：
Kuang Dai-Zhi
作者机构：
[Deng Yi-Fang; Chen Man-Sheng; Kuang Dai-Zhi; Zhang Chun-Hua; Tang Si-Ping] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Kuang Dai-Zhi] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
关键词：
锰配合物;晶体结构;5-二甲基苯甲酸;水热合成
摘要：
The title compound, [Mn3(L)6(CH3OH) 2]n·0.5nH2O (1), where HL=3,5-dimethylbenzoic acid, was synthesized and its crystal structure was determined by X-ray diffraction structure analysis. The crystal is of triclinic, space group P1 with a=1.275 1(13) nm, b=1.354 6(14) nm, c=1.882 3(19) nm, α=110.826(1)°, β=94.358(2)°, γ=108.038(1)°, V=2.825 4(5) nm3, Z=1, Mr=2 265.77, Dc=1.332 g·cm-3, μ=0.723 mm-1, F(000)=1 180, R int=0.037, R=0.056 4, wR=0.128 5. In the crystal the manganese atom is six-coordinated by six oxygen atoms, completing an octahedral geometry. The molecules are connected by 3,5-dimethylbenzoic acid to form a 1D chain structure bridged. CCDC: 694097.
摘要：
The title compound, [Mn_4(O_2CH)_4(phen)_8](ClO_4)_4·6H_2O (1), where phen= 1,10-phenanthroline, was synthesized and its crystal structure was determined by X-ray diffraction structure analysis. The crystal is of monoclinic, space group P2/c with a= 1.928 0(16) nm, b = 1.297 0(11) nm, c =2.126 4(18) nm, V=5.242 2(8) nm~3, Z=2, M_r=2 347.36,D, c=1.487 g·cm~(-3)，μ=0.659 mm-1, F(000)=2 400, R_(int)=0.043 7, R=0.052 3, wR=0.118 6. The Mn atoms are octahedrally coordinated by two O atoms of two ligands and four N atoms of two 1,10-phenanthroline molecules. The carboxyl group coordinates to Mn(Ⅱ) in the bridging bidentate mode. CCDC: 675520.
摘要：
The title complex {[(C_6H_5CH_2)_4Sn_2(OOCC_9H_(11))(ONHCH_2C_6H_5)]O}_2 (C_9H_(11)COO= 2,4,6- trimethylbenzolicate) has been synthesized by the reaction of bis-benzyltin oxide with 2,4,6-trimethylbenzolic acid and N-benzylhydroxylamine in 1:1:1 molar radio (C_(45)H_(47)NO_4Sn_2) and characterized by IR,1H NMR spectra and elemental analysis,and its crystal structure was determined by X-ray diffraction.It crystallizes in monoclinic,space group P2_1/c with a = 1.5654(5),b = 1.6467(6),c = 1.7433(6) nm,β = 111.729(5)°,Z= 2,V= 4.175(2) nm~3,M_r = 903.22,D_c = 1.437g/cm~3,μ = 1.238 mm~(-1),F(000) = 1824,R = 0.0440 and wR = 0.0906.The structure shows that the central tin atom is five-coordinated to assume a distorted trigonal bipyramidal configuration.The compound belongs to centrosymmetric dimer structure with four-membered central endo-cyclic Sn2O2 units in which the bridging oxygen atoms are tri-coordinated.
作者机构：
[Zhang Chun-Hua] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.;Hunan Inst Technol, Dept Chem Engn, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Zhang Chun-Hua] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
关键词：
锰配位聚合物;水热法;晶体结构
摘要：
A manganese coordination polymer [Mn(3,5-Me2PhCO2)(2)(phen)](n)(phen=1,10-phenanthroline) has been synthesized by hydrothermal methods. The crystal structure was determined by single-crystal X-ray diffraction. The crystal is of triclinic, space group P1 with a=0.7703(4) nm, b=1.1452(6) nm, c=1.5370(9) nm, alpha=78.182(9)degrees, ss= 77.170(9)degrees, gamma=89.784(9)degrees, V=1.2928(12) nm(3), Z=2, M-r=533.47,D-c=1.370g center dot cm(-3), mu=0.549 mm(-1), F(000)=554, R-int= 0.0434, R=0.0608 wR=0.148 4. In the crystal the manganese atom is six-coordinated by two nitrogen atoms from phen and four oxygen atoms from four 3,5-dimethylbenzolate molecules, completing an octahedral geometry. And the title complex forms one-dimensional chain structure through bridging 3,5-dimethylbenzolate molecules.
作者机构：
[Zhang C.-H.; Kuang D.-Z.; Feng Y.-L.; Xu J.-S.; Peng Y.-L.] Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China
通讯机构：
[Xu, J.-S.] D;Department of Chemistry and Materials Science, Hengyang Normal University, China
