作者机构:
[Kuang, Yun-Fei; Li, Wei; Yang, Ying-Qun] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.;[Li, Chang-Hong] Hunan Inst Technol, Dept Mat & Chem Engn, Hengyang 421002, Peoples R China.
通讯机构:
[Yang, Ying-Qun] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
摘要:
C21H21ClCuN3O5.5, triclinic, P (1) over bar (no. 2), a = 8.605(4) angstrom, b = 8.865(4) angstrom, c = 15.136(6) angstrom, alpha = 99.107(3)degrees, beta = 102.494(6)degrees, gamma = 106.571(7)degrees, V= 1050.2 angstrom(3), Z = 2, R-gt(F)= 0.028, wR(ref)(F-2) = 0.072, T = 113 K.
通讯机构:
[Tang, Si-Ping] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
摘要:
The title complex, [CuFe(C(5)H(5))(C(20)H(14)N(3))(C(12)H(8)N(2))](ClO(4))(2).C(2)H(3)N, consists of a mononuclear [Cu(C(12)H(8)N(2))(C(25)H(19)FeN(3))](2+) cation, two ClO(4) (-) anions (one of which is disordered over two positions with equal occupancy) and one CH(3)CN solvent mol-ecule. The Cu(II) center has a distorted square-pyramidal coordination with three N atoms of the 4'-ferrocenyl-2,2':6',2''- terpyridine (fctpy) ligand and one 1,10-phenanthroline (phen) N atom in the basal plane and a second phen N atom in the apical position with an axial distance of 2.254 (4) A. The disordered ClO(4) (-) anion is weakly coordin-ated to the Cu(II) ion with a Cu-O distance of 2.766 (11) A. The two cyclo-penta-dienyl rings of the ferrocenyl group are almost eclipsed with a deviation of 4.7 (1) degrees , and are involved in inter-molecular pi-pi inter-actions with the outer pyridyl rings of the fctpy ligands [centroid-centroid distance = 3.759 (2) A.].
通讯机构:
[Tang, Si-Ping] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
摘要:
In the title compound, C26H23N, the complete molecule is generated by crystallographic mirror symmetry, with the N atom and four C atoms lying on the reflection plane. The dihedral angles between the pyridine ring and pendant benzene rings are 2.9 (1), 14.1 (1) and 14.1 (1)°. Neighbouring mol-ecules are stabilized through inter-molecular π-π inter-actions along the c axis [centroid-to-centroid distance = 3.804 (2) Å], forming one-dimensional chains.
作者机构:
[Chen, Zhi-Min; Tang, Si-Ping; Kuang, Dai-Zhi; Feng, Yong-Lan; Li, Wei] Hengyang Normal Univ, Dept Chem & Mat Sci, Hunan 421008, Peoples R China.
通讯机构:
[Tang, Si-Ping] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hunan 421008, Peoples R China.
摘要:
The molecule of the title compound, C15H16N2O, is non-planar with a dihedral angle of 16.0 (1)° between the pyrrole and benzene rings. The ketone double-bond displays an s-cis conformation with an O=C - C=C torsion angle of 7.9 (3) and an intramolecular C - H⋯O hydrogen bond. In the crystal structure, adjacent mol-ecules are paired through N - H⋯O hydrogen bonds into centrosymmetric dimers.
摘要:
A one-dimensional chain coordination polymer [Co(II)(C_6H_5CH=CHCOOH)_2(4,4′- bipy)(H_2O)_5]n has been synthesized with cinnamylic acid, 4,4′-bipy and cobaltous chloride as raw materials. Crystal data for this complex: monoclinic, space group P21/c, a = 1.1481(3), b = 1.1230(2), c = 1.1759(3) nm, β = 97.054(4)o, V = 1.5046(6) nm~3, Mr= 617.50, Dc = 1.363 g/cm~3, Z = 2, μ(MoKα) = 0.627 mm~(-1), F(000) = 646, S = 1.062, R 0.0443 and wR = 0.1178. The crystal structure shows that two neighboring cobalt(II) ions are linked together by one 4,4′-bipy, and the whole complex molecule adopts a one-dimensional chain structure. Each cobalt(II) ion is coordinated with two nitrogen atoms from two 4,4′-bipy molecules and four oxygen atoms from four water molecules, giving a distorted octahedral coordination geometry. The electrochemical properties were analyzed by combining with the crystal structure.