摘要：
Three Co(II) complexes [Co(meophtpy)(2)](ClO4)(2)center dot 2CH(3)CN (1), [Co(nh(2)phtpy)(2)](ClO4)(2)center dot 2CH(3)CN (2), [Co(ftpy)(2)](ClO4)(2)center dot 2CH(3)CN (3) and three Mn(II) complexes [Mn(nme(2)phtpy)(2)]center dot(ClO4)(2)center dot 2CH(3)CN (4), [Mn(ftpy)(2)](ClO4)(2)center dot CH3CN (5), [Mn(meophtpy)(H2O)(NO3)(2)]center dot CH3CN (6) (meophtpy, 4'-(4-methoxyphenyl)- 2,2':6', 2 ''-terpyridine; nh(2)phtpy, 4'-(4-aminophenyl)-2,2':6',2 ''-terpyridine; ftpy, 4'-(furan2-yl)-2,2':6,2 ''-terpyridine; nme(2)phtpy, 4'-(4-(N,N-dimethylamino phenyl)-2,2':6',2 ''-terpyridine) are synthesized and their structures are determined by single crystal X-ray diffraction. Crystal data for 1 are: monoclinic, space group C2/c, a = 14.4781(5) angstrom, b = 16.2221(7) angstrom, c = 21.3617(9) angstrom, and Z = 4. For 2: monoclinic, space group C2/c, a = 14.554(6) angstrom, b = 15.239(6) angstrom, c = 21.754(9) angstrom, and Z = 4. For 3: monoclinic, space group C2/c, a = 14.5285(16) angstrom, b = 15.3234(16) angstrom, c = 21.154(2) angstrom, and Z = 4. For 4: triclinic, space group P-1, a = 12.132(5) angstrom, b = 12.536(5) angstrom, c = 17.840(10) angstrom, and Z = 2. For 5: triclinic, space group P-1, a = 9.993(10) angstrom, b = 13.950(13) angstrom, c = 15.511(15) angstrom, and Z = 2. For 6: monoclinic, space group Pc, a = 12.402(7) angstrom, b = 12.919(8) angstrom, c = 7.893(5) angstrom, and Z = 2. In complexes 1-5, Co(II) or Mn(II) ions are coordinated by six N atoms from two terpyridine moieties. In complex 6 the Mn(II) atom coordinates only one terpyridine ligand. All these complexes are linked by hydrogen bonds and face-to-face pi-pi interactions into three-dimensional networks. In complexes 4-6 the available solvent areas imply their potential applications in gas adsorption or catalysis.
作者机构：
[Mansheng Chen; Chunhua Zhang; Weiwei Fu; Dongcheng Liu; Fupei Liang] Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, College of chemistry and Materials Science;[Mansheng Chen; Chunhua Zhang; Weiwei Fu; Dongcheng Liu; Fupei Liang] Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry and pharmaceutical Sciences, Guangxi Normal University
会议名称：
The 4th International Congress on Advanced Materials (AM2018)
会议时间：
2018-11-15
会议地点：
中国江苏镇江
摘要：
As we know, metal-organic frameworks(MOFs) are new generation of porous materials which are constructed via the coordination bonds between metal ions/clusters and organic functional ligands.For MOFs,
作者机构：
[Fu, Wei-Wei; Peng, Yong-Qiong; Li, Yu-Ming; Li, Juan; Liu, Yang; Li, Xiao-Yan] Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, People's Republic of China
通讯机构：
[Fu, W.-W.] K;Key Laboratory of Functional Organometallic Materials of General Colleges, Universities in Hunan Province, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang, China
摘要：
Two complexes [Ag(bpy)(H2O)](Hbac) (1) and [Ag-2(bpy)(2)(H2O)(2)](pdc)(H2O)(5) (2) (H(2)bac = benzilic acid, bpy = 4,4 '-bypyridine, H(2)pdc = 2,6-pyridinedicarboxylic acid) have been synthesized and characterized by IR, element analysis, X-ray-single crystal diffraction and TGA. Crystal data for 1: Monoclinic, space group C2/c, alpha = 18.8192(5) a, b = 12.7131(5) a, c = 17.8373(8) a, beta = 95.745(4), V = 4246.1(3) a(3) and Z = 8; 2: Triclinic, space group, P-1, alpha = 8.132(5) a, b = 10.485(6) a, c = 18.026(10) a, alpha = 96.194(10), beta = 91.047(11), gamma = 105.866(10), V = 1468.0(15) a(3) and Z = 2. In complex 1, Ag(I) is coordinated by two discrete 4,4'-bpy ligands and one water molecule and Hbac(-) behaves as a counterpart anion. In the crystal, a 3D network was formed by hydrogen bonds and pi pi face-to-face interactions. In complex 2, Ag(I) is also coordinated by two discrete 4,4'-bpy ligands and one water molecule and pdc(2-) behaves as a counterpart anion, too. In the crystal, a similar 3D network was formed by hydrogen bonds and pi pi face-to-face interactions as well as that of complex 1. The luminescence properties of 1 and 2 have been investigated.
摘要：
A complex [Ni(meophtpy)(2)](ClO4)(2)center dot 2H(2)O (1) (meophtpy = 4'-(4-methoxyphenyl)-2,2':6',2 ''-terpyridine) has been synthesized and characterized by IR, element analysis, TGA and single crystal X-ray diffraction. The complex crystallizes in Tetragonal system with space group I4(1)/a, a = 24.470(4), b = 24.470(4), c = 13.845(5)angstrom, V = 8290.12 angstrom(3), Dc = 1.558 g/cm(3), Z = 8, F(000) = 4016, final GOF = 1.021, R-1 = 0.0619, and wR(2) = 0.1261 for 3616 observed reflections with I > 2 sigma(I). The crystal structure analysis shows that a three dimensional network overlapped with terpyridine motifs was formed by hydrogen bonds and pi-pi interactions which are seldom found in terpyridine complexes. Themagnetic property of 1 has also been investigated.
作者：
Fu, W. W.*;Huang, Q.;Liu, S. T.;Wu, W. J.;Shen, J. R.;...
期刊：
Russian Journal of Coordination Chemistry,2017年43(10):670-678 ISSN：1070-3284
通讯作者：
Fu, W. W.
作者机构：
[Fu, W. W.; Huang, Q.; Shen, J. R.; Li, S. H.; Wu, W. J.; Liu, S. T.] Hengyang Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Organometall Mat, Hunan Prov Coll, Hengyang 421008, Peoples R China.
通讯机构：
[Fu, W. W.] H;Hengyang Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Organometall Mat, Hunan Prov Coll, Hengyang 421008, Peoples R China.
摘要：
The bifunctional pyridine-2,3-dicarboxylic acid (H(2)pdc) ligand has one N atom and four O atoms, which could bind more than one Ag-I centre with diverse binding modes. A novel infinite one-dimensional Ag-I coordination polymer, namely catena-poly[[silver(I)-(mu(2)-pyridine-2,3-dicarboxylato-kappa N-2:O-3)-silver(I)tris(mu(2)-5-methyl-1,3,4-thiodiazol-2-amine-kappa(2) N:N')] monohydrate ethanol monosolvate], {[Ag-2(C7H3NO4)(C3H5N3S)(3)]center dot H2O center dot C2H5OH}(n), has been synthesized using H(2)pdc and 5-methyl-1,3,4-thiadiazol-2-amine (tda), and characterized by single-crystal X-ray diffraction. One Ag-I atom is located in a four-coordinated AgN4 tetrahedral geometry and the other Ag-I atom is in a tetrahedral AgN3O geometry. A dinuclear Ag-I cluster formed by three tda ligands with a paddelwheel configuration is bridged by the dianionic pdc(2-) ligand into a one-dimensional coordination polymer. Interchain N-H center dot center dot center dot O hydrogen bonds extend the one-dimensional chains into an undulating two-dimensional sheet. The sheets are further packed into a three-dimensional supramolecular framework by interchain N-H center dot center dot center dot O hydrogen bonds.
摘要：
Five coordination complexes [Fe(ftpy)(2)] (ClO4)(2) center dot (H2O)(2) (1), [Cu(ftpy)(NO3)(H2O)](NO3) (2), [Cu(ftpy)(2)](2) (ClO4)(4) center dot (C2H5OH) (3), [Zn(ftpy)(2)] center dot (ClO4)(2) center dot (H2O)(1.5) (4) and [Cd(ftpy)(2)](2) (ClO4)(4) center dot (C2H5OH) (5) (ftpy= 4'-(furan-2-yl)-2,2':6', 2 ''-terpyridine) have been synthesized and characterized by IR, elemental analysis and single-crystal X-ray diffraction. With the exception of 4, all complexes adopt normal homoleptic [M(ftpy)2](2+) motifs. In the crystal, both hydrogen bonds and face-to-face interactions between furyl and pyridyl rings facilitate the construction of three-dimensional networks. The DNA-binding activities of the five complexes have been investigated by fluorescence emission titration at room temperature suggesting an intercalative mode for 1-3 with a relative order, 3 > 2 > 1, and a combined static and dynamic mode for 4 and 5.
作者：
Fu, W. W.*;Cheng, Q. W.;Wang, H. Y.;He, F. Z. R.;Liu, Y.;...
期刊：
Russian Journal of Coordination Chemistry,2017年43(8):547-558 ISSN：1070-3284
通讯作者：
Fu, W. W.
作者机构：
[Zhang, F. X.; Fu, W. W.; Cheng, Q. W.; He, F. Z. R.; Liu, Y.; Wang, H. Y.] Hengyang Normal Univ, Dept Chem & Mat Sci, Hunan Prov Coll, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.
通讯机构：
[Fu, W. W.] H;Hengyang Normal Univ, Dept Chem & Mat Sci, Hunan Prov Coll, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.
摘要：
Four homoleptic copper(II) complexes, [Cu(Meophtpy)2](ClO4)2 (Meophtpy = 4′-(4-methoxylphenyl)- 2,2′:6′,2″-terpyridine) (I), [Cu(Meophtpy)2](ClO4)2 · 2H2O (II), [Cu2(m-Clphtpy)4](ClO4)4 (m-ClPhtpy = 4′-(3-chlorophenyl)-2,2′:6′,2″-terpyridine) (III), and [Cu2(m-ClPhtpy)4](ClO4)4 (IV) have been synthesized by hydrothermal methods and characterized by IR, elemental analysis and single crystal X-ray diffraction (CIF files CCDC nos. 963375 (I), 885457 (II), 963377 (III), and 963376 (IV)). Complex II is a polymorph of I and complex IV is a polymorph of III. All these complexes are obtained with 95% ethanol solution or 50% ethanol solution and the solvent control on the crystallization are obviously found. In all complexes, the face-to-face interactions between pyridyl rings or phenyl rings facilitate the construction of 3D network in the crystal in addition to hydrogen bonds. The fluorescence properties of these complexes have been investigated.
作者机构：
[Fu, Wei-Wei; Li, Ya-Qian; Li, Wei; Yang, Ying-Qun; Liu, Yang; Chen, Man-Sheng] Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province, Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, People's Republic of China
通讯机构：
[Fu, W.-W.] K;Key Lab. of Funct. Organometallic Materials of General Colleges and Universities in Hunan Province, Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, China
