The synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN based coatings
作者：
Chen, Yu;Zhang, Zhijian;Yuan, Tiechui;Mei, Fangsheng;Lin, Xiaoliang;...
期刊：
Surface and Coatings Technology ,2021年412:127082 ISSN：0257-8972
通讯作者：
Tiechui Yuan<&wdkj&>Fangsheng Mei
作者机构：
[Zhang, Zhijian; Chen, Yu; Yuan, Tiechui; Mei, Fangsheng] Cent South Univ, Powder Met Res Inst, Changsha 410083, Hunan, Peoples R China.;[Zhang, Zhijian] Hengyang Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421001, Hunan, Peoples R China.;[Gao, Jiangxiong; Lin, Xiaoliang] Zhuzhou Huarui Precis Cutting Tools Co Ltd, Zhuzhou 412000, Hunan, Peoples R China.;[Chen, Weifei] Zhuzhou Smelter Grp Co Ltd, Zhuzhou 412000, Hunan, Peoples R China.;[Xu, Yunbao] Hunan Inst Engn, Xiangtan 411100, Hunan, Peoples R China.
通讯机构：
[Tiechui Yuan; Fangsheng Mei] P;Powder Metallurgy Research Institute, Central South University, Changsha, Hunan 410083, PR China
关键词：
AlCrVSiN;Synergy;Microstructure;Tribological property;Oxidation resistance
摘要：
More and more attention has been paid to AlCrN coatings with self-lubricating property and high temperature oxidation resistance. In this study, the synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN coatings is investigated in detail. With V is gradually replaced by Si, coatings' microstructures are transformed from compact columnar to coarse columnar, and a dense fine-grained structure, and finally to a featureless dense structure. When the V content is 10 at.%, the coating is consisted of c-VN and c-Al(Cr)N solid solution phases. As decreasing the ratio of V to Si, there is only a cubic Al-Cr-V-N solid solution phase in Al0.58Cr0.31V0.08Si0.03N coating and the coexistence of c-Al(Cr)N and h-Al(Cr)N phases in Al0.58Cr0.31V0.04Si0.07N coating. The addition of Si can promote the transition from c-Al(Cr)N solid solution to h-Al(Cr)N solid solution, and finally forming a nanocomposite structure composed of h-Al(Cr)N nanocrystalline and alpha-Si3N4 for Al0.58Cr0.32Si0.1N coating. The performance test results indicate that the Al0.58Cr0.31V0.04Si0.07N coating has the best resistance to plastic deformation, the lowest wear rate of 2.72 x 10(-16) m(3).N-1.m(-1) and the oxidation resistance temperature of 1000 degrees C attributing to the synergistic effect of V and Si.
语种：
英文
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Striped Non-Uniform Corrosion Behavior of Non-Equiatomic FeMnCoCr High-Entropy Alloy Prepared by Laser Melting Deposition in 0.1 M H2SO4 Solution
作者：
Zhang, Zhijian;Yuan, Tiechui* ;Li, Ruidi*
期刊：
Materials ,2020年13(23):1-17 ISSN：1996-1944
通讯作者：
Yuan, Tiechui;Li, Ruidi
作者机构：
[Zhang, Zhijian; Li, Ruidi; Yuan, Tiechui; Li, RD] Cent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China.;[Zhang, Zhijian] Hengyang Normal Univ, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421001, Peoples R China.
通讯机构：
[Yuan, TC; Li, RD] C;Cent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China.
关键词：
Chromium alloys;Chromium metallography;Chromium metallurgy;Cobalt alloys;Cobalt metallography;Cobalt metallurgy;Corrosive effects;Deposition;Electrochemical corrosion;Electrochemical impedance spectroscopy;Entropy;Grain boundaries;High-entropy alloys;Iron alloys;Iron metallography;Iron metallurgy;Manganese alloys;Manganese metallography;Manganese metallurgy;Melting;Morphology;Scanning electron microscopy;Sulfuric acid;Corrosion performance;Electrochemical impedance spectroscopy measurements;Electron backscatter diffraction technique;Grain boundary regions;Laser melting deposition;Metallurgical defects;Non-uniform corrosions;Open circuit potential;Localized corrosion
摘要：
The corrosion behavior of the Fe50Mn30Co10Cr10 high-entropy alloy (HEA) manufactured via laser melting deposition (LMD) was investigated using open circuit potential, potentiodynamic polarization, and electrochemical impedance spectroscopy measurements. The microstructure and morphology of LMD samples before and after the electrochemical tests were compared using X-ray diffraction, optical microscopy, scanning electron microscopy, and electron backscatter diffraction techniques. After the corrosion tests, a striped morphology was observed on the surface of the LMD HEA, which is mainly caused by the interval distribution of high-density and low-density grain-boundary regions. The corrosion performances varied with different planes of the LMD HEA sample, which is mainly controlled by the grain size at each plane. Local corrosion in this HEA is concentrated at the melt pool boundary, which may be due to the abundant metallurgical defects and stress concentration at this location. © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This.
语种：
英文
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电石渣溶解过程中OH^-的溶出研究
作者：
柳科;杨建;周宏达;张志坚;蒋伍玖;...
期刊：
河南化工 ,2018年35(11):18-20 ISSN：1003-3467
作者机构：
湖南湘衡盐化有限责任公司,湖南衡阳,421006;衡阳师范学院化学与材料科学学院,湖南衡阳,421008;[张志坚; 蒋伍玖; 刘洋; 周宏达] 衡阳师范学院;[杨建; 柳科] 湖南省湘衡盐化有限责任公司
关键词：
电石渣;OH^-的溶出
摘要：
电石渣是电石水解获取乙炔后产生的一种工业废渣，主要成分是氢氧化钙，为了电石渣的合理回用并减少其对环境的污染，从溶出温度、搅拌速度、搅拌时间等因素研究了电石渣中OH^-的溶出情况，进而得出电石渣中OH^-溶出的最佳条件，为有效利用电石渣中氢氧化钙成分提供依据。
语种：
中文
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Synthesis, crystal structure and anticancer activity of the dibutyltin(IV)oxide complexes containing substituted salicylaldehyde-o-aminophenol Schiff base with appended donor functionality
作者：
Zhang, Zhi-Jian;Zeng, Hui-Ting;Liu, Yang;Kuang, Dai-Zhi;Zhang, Fu-Xing;...
期刊：
Inorganic and Nano-Metal Chemistry ,2018年48(10):486-494 ISSN：2470-1556
通讯作者：
Tan, Yu-Xing;Jiang, Wu-Jiu
作者机构：
[Tan, Yu-Xing; Jiang, WJ; Zhang, Fu-Xing; Jiang, Wu-Jiu; Kuang, Dai-Zhi; Liu, Yang; Zhang, Zhi-Jian] Hengyang Normal Univ, Coll Chem & Mat Sci, Univ Hunan Prov, Key Lab Funct Met Organ Cpds Hunan Prov,Key Lab F, Hengyang 421008, Hunan, Peoples R China.;[Zeng, Hui-Ting] Sch Med Technol, Hengyang, Hunan Polytech Environm & Biol, Hengyang, Hunan, Peoples R China.
通讯机构：
[Tan, YX; Jiang, WJ] H;Hengyang Normal Univ, Coll Chem & Mat Sci, Univ Hunan Prov, Key Lab Funct Met Organ Cpds Hunan Prov,Key Lab F, Hengyang 421008, Hunan, Peoples R China.
关键词：
anticancer activity;crystal structure;organotin;Schiff base;synthesis
摘要：
Schiff base butyltin complexes C1 ∼ C3 have been synthesized via the reaction of dibutyltin oxide with the substituted salicylaldehyde-o-aminophenol Schiff base ligands (L1 ∼ L3), respectively. The complexes have been characterized by elemental analysis, IR, UV-Vis, 1 H NMR, 13C NMR spectra and the crystal structures have been determined by X-ray diffraction. The anticancer activity of the Schiff base ligands L1 ∼ L3 and complexes C1 ∼ C3 against five species of cancer cells which are MCF7, Colo205, NCI-H460, Hela and HepG2 were tested respectively, the tests showed that C3 exhibited significant anticancer activity for the cancer cells in comparison with other complexes. The interaction between C3 and calf thymus DNA were studied by fluorescence, UV-Vis and Viscosity experiment, the results show that the interaction of C3 with calf thymus DNA was intercalation. © 2019, © 2019 Taylor & Francis Group, LLC.
语种：
英文
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N-(2-丙酸)-芳甲酰腙二对甲基苄基锡配合物的合成、晶体结构及生物活性
作者：
Zhang Zhi-Jian;Jiang Wu-Jiu;Liu Yang;Kuang Dai-Zhi;Yu Jiang-Xi;...
期刊：
无机化学学报 ,2017年33(9):1603-1610 ISSN：1001-4861
通讯作者：
Tan Yu-Xing
作者机构：
[Liu Yang; Jiang Wu-Jiu; Kuang Dai-Zhi; Zhang Zhi-Jian; Tan Yu-Xing; Yu Jiang-Xi; Zhu Xiao-Ming] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Coll Hunan Prov, Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Tan Yu-Xing] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Coll Hunan Prov, Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
关键词：
有机锡配合物;酰腙;合成;晶体结构;生物活性
摘要：
二对甲基苄基二氯化锡分别与N-(2-丙酸)-对硝基苯甲酰腙及N-(2-丙酸)-对叔丁基苯甲酰腙反应,合成了2个取代二苄基锡配合物(C1、C2),通过元素分析、IR、UV-Vis、~1H NMR、~(13)C NMR、~(119)Sn NMR、X射线单晶衍射以及热重分析等表征了配合物结构。测试了配合物对癌细胞H460、HepG2、MCF7以及正常人体肝细胞HL7702的体外抑制活性;在Tris-HCl缓冲溶液中,以EB作为荧光探针,用荧光光谱法初步研究了配合物与小牛胸腺DNA的相互作用。结果表明:配合物C1、C2对3种癌细胞都有较好的抑制作用,配合物C2对HL7702的细胞毒性远小于C1;配合物C1、C2与小牛胸腺DNA作用均是插入结合作用所致。
语种：
中文
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一种2??羰基丁酸对甲氧基苯甲酰腙二苯基锡配合物及其制备方法和应用
发明/设计人：
谭宇星;蒋伍玖;张志坚;张复兴;邝代治;...
申请/专利权人：
衡阳师范学院
申请/专利号：
CN201610753673.3
申请时间：
2016-8-30
公开号：
CN106366120A
公开时间：
2017-02-01
主申请人地址：
421002 湖南省衡阳市珠晖区衡花路16号
摘要：
本发明公开了一种2??羰基丁酸对甲氧基苯甲酰腙二苯基锡配合物，为如下结构式(I)的配合物<img file="730938dest_path_image002.TIF" wi="146" he="212" />，其中R为苯基。本发明还公开了该2??羰基丁酸对甲氧基苯甲酰腙二苯基锡配合物的制备方法和在制备抗癌药物中的应用。
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Syntheses, Crystal Structures and Biological Activity of the 1D Chain Benzyltin Complexes Based on 2-Oxo-Propionic Acid Benzoyl Hydrazone
作者：
Tan, Yu-Xing;Zhang, Zhi-Jian;Feng, Yong-Lan;Yu, Jiang-Xi;Zhu, Xiao-Ming;...
期刊：
Journal of Inorganic and Organometallic Polymers and Materials ,2017年27(1):342-352 ISSN：1574-1443
通讯作者：
Jiang, Wu-Jiu
作者机构：
[Zhang, Fu-Xing; Jiang, Wu-Jiu; Kuang, Dai-Zhi; Tan, Yu-Xing; Feng, Yong-Lan; Zhang, Zhi-Jian; Yu, Jiang-Xi; Zhu, Xiao-Ming] Hengyang Normal Univ, Coll Hunan Prov, Coll Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Jiang, Wu-Jiu] H;Hengyang Normal Univ, Coll Hunan Prov, Coll Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
关键词：
Bioactivity;Cell culture;Chains;Chemical compounds;Complexation;Diseases;Nuclear magnetic resonance spectroscopy;Organometallics;Single crystals;Synthesis (chemical);Thymus;Tin;Anti-tumor activities;Chemical optimizations;Electrostatic attractions;Fluorescent probes;Human cancer cells;Hydrazones;Organotins;X-ray single-crystal diffraction;Crystal structure
摘要：
Two new 1D Chain benzyltin complexes {[C6H4(O)C=N–N=C(Me)COO](CH3OH)(C6H5CH2)2Sn}n (1), {[C6H4(O)C–NH–N=C(Me)COO](C6H5CH2)3Sn}n (2) were synthesized by the reactions of 2-oxo-propionic acid benzoyl hydrazone with dibenzyltin dichloride or tribenzyltin chloride, respectively. The two complexes were characterized by FT-IR, 1H, 13C and 119Sn NMR spectra, elemental analysis, X-ray single crystal diffraction and TGA. In vitro antitumor activities of both complexes were evaluated by the 3-(4,5-dimethylthiazoly-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay against three human cancer cell lines (NCI-H460, HepG2, MCF7) and human cell line (HL7702). The 1 exhibited strong antitumor activity than 2, then it was expected after further chemical optimization of candidate compounds as anti-cancer drugs. The interaction between complexes and calf thymus DNA were studied by EB fluorescent probe, the interaction of 1 and 2 with calf thymus DNA were intercalation and electrostatic attraction. © 2016, Springer Science+Business Media New York.
语种：
英文
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Syntheses, Crystal Structures and Biological Activities of the 2-Oxo-butyric Acid Salicylacylhydrazone Dibenzyltin Complexes
作者：
Tan Yu-Xing;Zhang Zhi-Jian;Feng Yong-Lan;Yu Jiang-Xi;Zhu Xiao-Ming;...
期刊：
Chinese Journal of Structural Chemistry ,2017年36(6):925-936 ISSN：0254-5861
通讯作者：
Jiang Wu-Jiu
作者机构：
[Jiang Wu-Jiu; Feng Yong-Lan; Kuang Dai-Zhi; Zhang Zhi-Jian; Tan Yu-Xing; Yu Jiang-Xi; Zhu Xiao-Ming] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Coll Hunan Prov, Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Jiang Wu-Jiu] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Coll Hunan Prov, Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
关键词：
organotin;hydrazone;synthesis;crystal structure;biological activity
摘要：
2-Oxo-butyric acid salicylacylhydrazone dibenzyltin (IV) complexes 1 {[o-OHC_6H_4(O)C=N-N=C(Et)COO](CH_3OH)[(C_6H_5CH_2)_2Sn]}_2 and 2 {[o-OH-C_6H_4(O)C=N-N=C(Et)-COO](CH_3OH)[(2,4-Cl_2C_6H_3CH_2)_2Sn]}_2 have been synthesized. The complexes were characterized by IR, 1H, 13C and 119Sn NMR spectra, elemental analysis and thermal stability analysis, and the crystal structures were determined by X-ray diffraction. The crystal of complex 1 belongs to triclinic system, space group P1 with a = 8.9121(6), b = 10.3875(7), c = 14.5658(10) A, α = 89.534(5), β = 86.790(5), γ = 70.103(6)°, Z = 1, V = 1265.85(15) A~3, D_c = 1.488 Mg·m~(-3), μ(MoKα) = 1.047 mm~(-1), F(000) = 576, R = 0.0466 and wR = 0.1054. The crystal of complex 2 belongs to monoclinic system, space group P_21/n, a = 12.7165(10), b = 17.8466(14), c = 12.8538(10) A, β = 95.1310(10)°, Z = 2, V = 2905.4(4) A~3, D_c = 1.612 Mg·m~(-3), μ(MoKα) = 1.286 mm~(-1), F(000) = 1408, R = 0.0369 and wR = 0.0958. In vitro antitumor activities of both complexes were evaluated by the 3-(4,5-dimethylthiazoly-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay against three human cancer cell lines (NCI-H460, HepG2, MCF7) and one human cell line (HL7702). Two complexes exhibited strong antitumor activity, and then they were expected after further chemical optimization of candidate compounds as anti-cancer drugs. The interaction between complexes and calf thymus DNA were studied by EB fluorescent probe. The interactions of the two complexes with calf thymus DNA were intercalation.
语种：
英文
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不对称四烃基锡化合物的合成及晶体结构
作者：
姚纪源;张志坚;蒋伍玖;庾江喜;冯泳兰;...
期刊：
山东化工 ,2017年46(3):11-13 ISSN：1008-021X
作者机构：
衡阳师范学院 化学与材料科学学院,湖南 衡阳,421008;衡阳师范学院 化学与材料科学学院,湖南 衡阳 421008;功能金属有机材料湖南省普通高等学校重点实验室,湖南 衡阳 421008;[庾江喜; 张志坚; 冯泳兰; 邝代治; 谭宇星; 蒋伍玖; 姚纪源] 衡阳师范学院
关键词：
有机锡;不对称;烃基锡;合成;晶体结构
摘要：
以氯苯、金属钠和无水四氯化锡为原料,通过Wurtz反应合成了四苯基锡（C1）,在经过Kocheskov再分配反应,合成了三苯基氯化锡,最后通过与甲基格氏试剂反应,合成了三苯基甲基锡（C2）。化合物经IR、元素分析、^1H NMR、^13C NMR、^119Sn NMR、X-射线单晶衍射表征结构,晶体衍射结果表明两个化合物的中心锡原子均为畸变四面体构型。
语种：
中文
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一种2??羰基??2??苯基乙酸对甲氧基苯甲酰腙二苯基锡配合物及其制备方法和应用
发明/设计人：
蒋伍玖;谭宇星;张志坚;邝代治;朱小明;...
申请/专利权人：
衡阳师范学院
申请/专利号：
CN201610747477.5
申请时间：
2016-8-29
公开号：
CN106349280A
公开时间：
2017-01-25
主申请人地址：
421002 湖南省衡阳市珠晖区衡花路16号
摘要：
本发明公开了一种2??羰基??2??苯基乙酸对甲氧基苯甲酰腙二苯基锡配合物，为如下结构式(I)的配合物<img file="dest_path_image002.TIF" wi="357" he="279" />，其中Ph为苯基。本发明还公开了该2??羰基??2??苯基乙酸对甲氧基苯甲酰腙二苯基锡配合物的制备方法和在制备抗癌药物中的应用。
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Synthesis, crystal structure and biological activity of the Schiff base organotin(IV) complexes based on salicylaldehyde-o-aminophenol
作者：
Tan, Yu-Xing;Zhang, Zhi-Jian;Liu, Yang;Yu, Jiang-Xi;Zhu, Xiao-Ming;...
期刊：
Journal of Molecular Structure ,2017年1149:874-881 ISSN：0022-2860
通讯作者：
Jiang, Wu-Jiu
作者机构：
[Jiang, Wu-Jiu; Kuang, Dai-Zhi; Tan, Yu-Xing; Liu, Yang; Zhang, Zhi-Jian; Yu, Jiang-Xi; Zhu, Xiao-Ming] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Coll Hunan Prov, Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Jiang, Wu-Jiu] H;Hengyang Normal Univ, Key Lab Funct Organometall Mat, Coll Hunan Prov, Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
关键词：
Organotin;Schiff base;Synthesis;Crystal structure;Biological activity
摘要：
Schiff base organotin(IV) complexes C1 ∼ C5b have been synthesized via the reaction of the substituted salicylaldehyde-o-aminophenol Schiff base ligands (L1 ∼ L3) with the dibenzyltin dichloride, n-butyltin trichloride or dibutyltin oxide, respectively. The complexes have been characterized by IR, UV–Vis, 1H NMR, 13C NMR spectra, elemental analysis and the crystal structures have been determined by X-ray diffraction. The anticancer activity of the Schiff base ligand and complexes C1 ∼ C5b against five species of cancer cell which are Hela, MCF7, HepG2, Colo205, NCI–H460 were tested respectively, the tests showed that C1 ∼ C5b exhibited significant anticancer activity for the cancer cells in comparison with the ligand, and the activity was greater than carboplatin. © 2017
语种：
英文
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Syntheses, crystal structures and biological activity of the dialkytin complexes based on 2-oxo-3-phenylpropionic acid salicyloylhydrazone
作者：
Tan, Yuxing;Zhang, Zhijian;Tan, Yuhuan;Kuang, Daizhi;Yu, Jiangxi;...
期刊：
Journal of Coordination Chemistry ,2017年70(15):2606-2624 ISSN：0095-8972
通讯作者：
Jiang, Wujiu
作者机构：
[Jiang, Wujiu; Tan, Yuxing; Yu, Jiangxi; Zhu, Xiaoming; Zhang, Zhijian; Kuang, Daizhi] Hengyang Normal Univ, Coll Hunan Prov, Key Lab Funct Organometall Mat, Hengyang, Peoples R China.;[Jiang, Wujiu; Tan, Yuxing; Yu, Jiangxi; Zhu, Xiaoming; Zhang, Zhijian; Kuang, Daizhi] Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang, Peoples R China.;[Tan, Yuhuan] Hunan Univ Sci & Technol, Coll Chem & Chem Engn, Xiangtan, Peoples R China.
通讯机构：
[Jiang, Wujiu] H;Hengyang Normal Univ, Coll Hunan Prov, Key Lab Funct Organometall Mat, Hengyang, Peoples R China.;Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang, Peoples R China.
关键词：
Organotin;hydrazone;synthesis;crystal structure;biological activity
摘要：
Three new dialkytin complexes, {[o-OH–C6H4(O)C=N–N=C(CH2Ph)COO](n-Bu2Sn)}n (1), {[o-OH–C6H4(O)C=N–N=C(CH2Ph)COO](MeOH)(p-MeC6H5CH2)2Sn}2 (2), and {[o-OH–C6H4(O)C=N–N=C(CH2Ph)COO](EtOH)(C6H5CH2)2Sn}2 (3), were synthesized by reactions of 2-oxo-3-phenylpropionic acid salicyloylhydrazone with the corresponding diorganotin(IV) complex, respectively. All the complexes were characterized by IR, 1H, 13C, 119Sn NMR spectra, elemental analysis, X-ray single crystal diffraction and TGA. For in vitro antitumor activities, complexes were evaluated by the MTT assay against three human cancer cell lines (NCI-H460, HepG2 and MCF7) and human cell line (HL7702). The results showed that 1 may be a better potential candidate for further chemical optimization and cancer therapy than 2 and 3. The interactions between the complexes and calf thymus DNA were studied; the interaction of 1 with calf thymus DNA was intercalation, 2 and 3 were intercalation and electrostatic binding. © 2017 Informa UK Limited, trading as Taylor & Francis Group.
语种：
英文
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一种2?羰基丙酸对甲氧基苯甲酰腙二(2,4?二氯苄基)锡配合物及其制备方法和应用
发明/设计人：
谭宇星;蒋伍玖;张志坚;庾江喜;张复兴;...
申请/专利权人：
衡阳师范学院
申请/专利号：
CN201610747205.5
申请时间：
2016-8-29
公开号：
CN106380479A
公开时间：
2017-02-08
主申请人地址：
421002 湖南省衡阳市珠晖区衡花路16号
摘要：
本发明公开了一种2??羰基丙酸对甲氧基苯甲酰腙二(2,4??二氯苄基)锡配合物，为如下结构式(I)的配合物<img file="dest_path_image002.TIF" wi="345" he="172" />，其中R为2,4??二氯苄基。本发明还公开了该2??羰基丙酸对甲氧基苯甲酰腙二(2,4??二氯苄基)锡配合物的制备方法和在制备抗癌药物中的应用。
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干、湿电石渣形貌及成分分析
作者：
杨建;柳科;张志坚;蒋伍玖;谭宇星;...
期刊：
山东化工 ,2017年46(19):89-90+92 ISSN：1008-021X
作者机构：
[张志坚; 谭宇星; 蒋伍玖; 刘洋] 湖南省湘衡盐化有限责任公司;衡阳师范学院化学与材料科学学院;[杨建; 柳科] 衡阳师范学院
关键词：
电石渣;形貌;成分;分析
摘要：
电石渣是工业上由电石制备乙炔后的产物,按照其再利用需要,可制成干、湿两种形态,本文通过IR,SEM,TGA等方法,比较了干、湿电石渣的形貌及成分差异,为综合利用干、湿电石渣提供了理论依据。
语种：
中文
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一种2‑羰基丙酸对甲氧基苯甲酰腙二苄基锡配合物及其制备方法和应用
发明/设计人：
蒋伍玖,谭宇星,张志坚,朱小明,邝代治,张复兴,庾江喜
申请/专利权人：
衡阳师范学院
申请/专利号：
CN201610735225.0
申请时间：
2016-8-28
公开号：
CN106220676A
公开时间：
2016-12-14
主申请人地址：
421002 湖南省衡阳市珠晖区衡花路16号
摘要：
本发明公开了一种2‑羰基丙酸对甲氧基苯甲酰腙二苄基锡配合物，为如下结构式(I)的配合物<img file="dest_path_image001.TIF" wi="146" he="219" />，其中R为苄基。本发明还公开了该2‑羰基丙酸对甲氧基苯甲酰腙二苄基锡配合物的制备方法和在制备抗癌药物中的应用。
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一种2??羰基丙酸对甲氧基苯甲酰腙二苯基锡配合物及其制备方法和应用
发明/设计人：
蒋伍玖;谭宇星;张志坚;朱小明;邝代治;...
申请/专利权人：
衡阳师范学院
申请/专利号：
CN201610747192.1
申请时间：
2016-8-29
公开号：
CN106336432A
公开时间：
2017-1-18
主申请人地址：
421002 湖南省衡阳市珠晖区衡花路16号
摘要：
本发明公开了一种2??羰基丙酸对甲氧基苯甲酰腙二苯基锡配合物，为如下结构式(I)的配合物<img file="dest_path_image002.TIF" wi="342" he="183" />，其中R为苯基。本发明还公开了该2??羰基丙酸对甲氧基苯甲酰腙二苯基锡配合物的制备方法和在制备抗癌药物中的应用。
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一种2??羰基丁酸对甲氧基苯甲酰腙二正丁基锡配合物及其制备方法和应用
发明/设计人：
谭宇星;蒋伍玖;张志坚;张复兴;邝代治;...
申请/专利权人：
衡阳师范学院
申请/专利号：
CN201610747490.0
申请时间：
2016-8-29
公开号：
CN106432323A
公开时间：
2017-2-22
主申请人地址：
421002 湖南省衡阳市珠晖区衡花路16号
摘要：
本发明公开了一种2??羰基丁酸对甲氧基苯甲酰腙二正丁基配合物，为如下结构式(I)的配合物<img file="dest_path_image002.TIF" wi="342" he="182" />，其中R为正丁基。本发明还公开了该2??羰基丁酸对甲氧基苯甲酰腙二正丁基配合物的制备方法和在制备抗癌药物中的应用。
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一种2??羰基丁酸对甲氧基苯甲酰腙二(2,4??二氯苄基)锡配合物及其制备方法和应用
发明/设计人：
谭宇星;蒋伍玖;张复兴;张志坚;邝代治;...
申请/专利权人：
衡阳师范学院
申请/专利号：
CN201610753181.4
申请时间：
2016-8-30
公开号：
CN106349281A
公开时间：
2017-1-25
主申请人地址：
421002 湖南省衡阳市珠晖区衡花路16号
摘要：
本发明公开了一种2??羰基丁酸对甲氧基苯甲酰腙二(2,4??二氯苄基)锡配合物，为如下结构式(I)的配合物<img file="506497dest_path_image002.TIF" wi="341" he="174" />，其中R为2,4??二氯苄基。本发明还公开了该2??羰基丁酸对甲氧基苯甲酰腙二(2,4??二氯苄基)锡配合物的制备方法和在制备抗癌药物中的应用。
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邻香草醛缩4-氯邻氨基苯酚Schiff碱正丁基锡配合物的合成、晶体结构及生物活性研究
作者：
谭宇星;张志坚;姚纪源;蒋伍玖;庾江喜;...
期刊：
衡阳师范学院学报 ,2016年37(06):70-74 ISSN：1673-0313
作者机构：
功能金属有机材料湖南省普通高等学校重点实验室，湖南 衡阳 421008;衡阳师范学院 化学与材料科学学院，湖南 衡阳 421008;衡阳师范学院 化学与材料科学学院,湖南 衡阳,421008;[庾江喜; 冯泳兰; 邝代治; 谭宇星; 蒋伍玖; 朱小明] 功能金属有机材料湖南省普通高等学校;[张志坚; 姚纪源] 衡阳师范学院
关键词：
有机锡（IV）配合物;Schiff碱;合成;晶体结构;生物活性
摘要：
利用邻香草醛缩4-氯邻氨基苯酚 Schiff碱(H2 L)和正丁基三氯化锡反应，合成了一个 Schiff碱正丁基锡配合物(C1)，通过元素分析、FT-IR、1 H NMR、13 C NMR以及 X-射线单晶衍射对合成的有机锡 Schiff碱配合物C1进行了表征。研究了配合物(C1)的紫外可见光谱，并且运用 MTT 方法，研究了该有机锡 Schiff碱配合物对癌细胞的体外抑制活性，研究的结果显示，该有机锡 Schiff 碱配合物 C1对 MCF7、NCI-H460的抑制活性相比卡铂要更优越，因而可以考虑经过化学优化后，作为抗癌药物的备选化合物。
语种：
中文
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一种2??羰基??3??苯基丙酸对甲氧基苯甲酰腙二苄基锡配合物及其制备方法和应用
发明/设计人：
谭宇星;蒋伍玖;张志坚;张复兴;邝代治;...
申请/专利权人：
衡阳师范学院
申请/专利号：
CN201610747512.3
申请时间：
2016-8-29
公开号：
CN106432324A
公开时间：
2017-2-22
主申请人地址：
421002 湖南省衡阳市珠晖区衡花路16号
摘要：
本发明公开了一种2??羰基??3??苯基丙酸对甲氧基苯甲酰腙二苄基锡配合物，为如下结构式(I)的配合物<img file="dest_path_image002.TIF" wi="345" he="182" />，其中Ph为苯基，R为苄基。本发明还公开了该2??羰基??3??苯基丙酸对甲氧基苯甲酰腙二苄基锡配合物的制备方法和在制备抗癌药物中的应用。
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