作者：
Yang Ying-Qun*;Li Chang-Hong;Li Wei;Yang Tian-Yi
期刊：
Chinese Journal of Structural Chemistry,2022年41(3):248-252 ISSN：0254-5861
通讯作者：
Yang Ying-Qun;Li, W;Li, CH
作者机构：
[Li Wei; Yang Ying-Qun] Hunan Prov Coll, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.;[Li Wei; Yang Ying-Qun] Hunan Prov Coll, Key Lab Funct Organomet Mat, Hengyang 421008, Peoples R China.;[Yang Tian-Yi; Li Wei; Yang Ying-Qun] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.;[Li Chang-Hong; Li, CH] Hunan Inst Technol, Sch Mat & Chem Engn, Hengyang 421002, Peoples R China.
通讯机构：
[Li, W ; Yang, YQ; Li, CH ] H;Hunan Prov Coll, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.;Hunan Prov Coll, Key Lab Funct Organomet Mat, Hengyang 421008, Peoples R China.;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.;Hunan Inst Technol, Sch Mat & Chem Engn, Hengyang 421002, Peoples R China.
关键词：
europium(III) complex;crystal structure;magnetic and fluorescent properties
摘要：
A new europium（III） complex [Eu2(C14H9O3)6（2，2’-bipy）2]·（2，2’-bipy）2 has been synthesized with 2-benzoylbenzoic acid and 2，2’-bipyridine as ligands. Crystal data: triclinic， space group P1， with a = 13.5251（5）， b = 13.9453（5）， c = 15.3582（5） ?， α = 76.922（3）o， β = 79.740（3）o， γ = 64.248（4）o， V = 2530.83（18） ?3， Dc = 1.496 g/cm3， Z = 1， μ（MoKα） = 1.305 mm-1， F（000） = 1156， the final R = 0.0340 and wR = 0.0638. The Eu（III） ion is coordinated by eight atoms to give a distorted square antiprism coordination geometry. The complex exhibits antiferromagnetism in the temperature range of 300～2 K， and two intense fluorescence emission bands arising from the transitions of Eu3+: 5D0 → 7F1 （595 nm） and 5D0 → 7F2 （618 nm）， respectively. In addition， the fluorescence sensing properties of the complex in CrO42- solution were studied.
作者：
Yang Ying-Qun*;Li Wei*;Yang Pin-Fang;Kuang Yun-Fei*
期刊：
Chinese Journal of Structural Chemistry,2020年39(6):1087-1092 ISSN：0254-5861
通讯作者：
Yang Ying-Qun;Li Wei;Kuang Yun-Fei
作者机构：
[Kuang Yun-Fei; Yang Ying-Qun; Li Wei; Kuang, YF] Univ Hunan Prov, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.;[Kuang Yun-Fei; Yang Ying-Qun; Li Wei; Kuang, YF] Univ Hunan Prov, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.;[Kuang Yun-Fei; Yang Pin-Fang; Yang Ying-Qun; Li Wei; Kuang, YF] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构：
[Yang, YQ; Li, W; Kuang, YF] U;[Yang, YQ; Li, W; Kuang, YF] H;Univ Hunan Prov, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.;Univ Hunan Prov, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
关键词：
terbium(III) complex;crystal structure;fluorescence and magnetic properties
关键词：
Ceramic;Glass;High temperature corrosion;Oxide coatings
摘要：
High-temperature degradation of the plasma sprayed LaMA coating before and after in-situ laser-glazing under CMAS attacks at 1350 degrees C for 1 h, 12 h and 48 h was comparatively investigated. Results indicate that a dense laser-glazed top layer was successfully created in-situ for a similar to 1 mm thick LaMA coating. It behaved as a sealing layer and reservoir of Al3+, Mg2+ and La3+. Melted CMAS penetration was accordingly effectively arrested accompanied by crystallizations of the CaAl2Si2O8 anorthite, MgAl2O4 spinel and Ca2La8(SiO4)(6)O-2 apatite. CMAS-induced degradation mainly occurred near the surface of the laser-glazed dense LaMA top layer. While significant penetration of the melted CMAS along the entire thickness occurred to the as-sprayed LaMA coating without laser-glazing treatments after 48 h degradation. Ca2La8(SiO4)(6)O-2 apatite phase did not crystallize for the as-sprayed LaMA due to the much reduced local La3+ concentration in melted CMAS resulted from its porous microstructure. Effects of laser-glazing on the CMAS-induced degradation of the plasma sprayed LaMA was carefully analyzed and discussed in terms of the coating's chemical composition, microstructure and surface physical chemistry characteristics base on XRD, SEM/EDS and TEM results.
期刊：
Chinese Journal of Structural Chemistry,2020年39(7):1331-1336 ISSN：0254-5861
通讯作者：
Yang Ying-Qun;Li Wei
作者机构：
[Yang Ying-Qun; Li Wei] Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.;[Yang Ying-Qun; Li Wei] Key Lab Funct Organometall Mat Hunan Prov Coll, Hengyang 421008, Peoples R China.;[Tuo Lu-Yao; Yang Ying-Qun; Li Wei] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构：
[Yang, YQ; Li, W] K;[Yang, YQ; Li, W] H;Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.;Key Lab Funct Organometall Mat Hunan Prov Coll, Hengyang 421008, Peoples R China.;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
关键词：
terbium(III) complex;crystal structure;fluorescent and magnetic properties
摘要：
A new terbium(III) complex Tb-2(C15H11O3)(6)(2,2'-bipy)(2) has been synthesized with 2-(4-methylbenzoyl)benzoic acid and 2,2'-bipy ligands. Crystal data for the complex: monoclinic, space group P2(1)/n, a = 14.9738(5), b = 13.5469(4), c = 23.0683(7) angstrom, beta= 103.950(3)degrees, V= 4541.4(3) angstrom(3) , D-c = 1.511 g/cm(3), Z = 2,mu(MoK alpha) = 1.620 mm(-1), F(000) = 2088, the final R= 0.0318 and wR = 0.0727. The Tb(III) ion is coordinated by eight atoms to give a distorted square antiprism coordination geometry. The complex shows three fluorescence emission bands arising from the transitions of Tb3+: D-5(4) -> F-7(6) (490 nm), D-5(4) -> F-7(5) (545 nm) and D-5(4) -> F-7(4) (584 nm). The complex exhibits antiferromagnetism in the temperature range of 300 similar to 2 K. Also reported are the thermal stability properties of the complex.
期刊：
Chinese Journal of Structural Chemistry,2019年38(12):2129-2134 ISSN：0254-5861
通讯作者：
Yang Ying-Qun;Li Wei
作者机构：
[Yang Ying-Qun; Li Wei] Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.;[Yang Ying-Qun; Li Wei] Hunan Prov Coll, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.;[Yang Ying; Li Jiao-Di; Yang Ying-Qun; Li Wei] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构：
[Yang, YQ; Li, W] K;[Yang, YQ; Li, W] H;Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.;Hunan Prov Coll, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
关键词：
terbium(III) complex;crystal structure;fluorescent and magnetic properties
摘要：
A new terbium(III) complex Tb(C20H14O3N)(3)(C12H8N2)(H2O)center dot H2O has been synthesized with 2-diphenylanine carbonyl benzoic acid and 1,10-phenanthroline as ligands. Crystal data for the complex are as follows: triclinic, space group P (1) over bar, a =11.6034(6), b = 16.2465(8), c = 16.4427(8) angstrom, alpha = 73.168(5)degrees, beta = 88.655(4)degrees, gamma = 82.865(4)degrees, V= 2943.7(3) angstrom(3), D-c = 1.494 g/cm(3), Z = 2, mu(MoK alpha) = 1.272 mm(-1), F(000) = 1348, the final R= 0.0535 and wR = 0.0809. The Tb(III) ion is coordinated by nine atoms to give a monocapped square antiprism coordination geometry. The complex shows four fluorescence emission bands arising from the transitions of Tb3+: D-5(4) -> F-7(6) (491 nm), D-5(4) -> F-7(5) (546 nm), D-5(4) -> F-7(4) (585 nm) and D-5(4) -> F-7(3) (621 nm). Also reported are the magnetic and thermal stability properties of the complex.
摘要：
A kind of coenzyme A (CoA)-silver coordination complex (CoA-Ag) was in-situ developed and verified to accelerate the electron transferring and electrochemical catalysis of H2O2 decomposition to enhance the cathode ECL intensity of CdTe@CdS QDs. Afterward, a convenient label-free signal-on ECL approach was constructed for CoA detection with excellent specificity. In addition, the unique ECL enhancing phenomenon was also proposed to assay the enzymatic activity of histone acetyltransferases (HAT) and screen relevant inhibitors, exhibiting a promising potential in the practical application of biochemical research, disease diagnosis and drug discovery.
作者：
Yan Jia-Jia;Li Chang-Hong;Li Wei*;Yang Zi-Tun;Li Ling;...
期刊：
Chinese Journal of Structural Chemistry,2019年38(10):1823-1827 ISSN：0254-5861
通讯作者：
Li Wei
作者机构：
[Yang Zi-Tun; Yan Jia-Jia; Li Ling; Liu He-Bao; Li Wei] Hengyang Normal Univ, Hengyang 421008, Peoples R China.;[Li Chang-Hong] Hunan Inst Technol, Sch Mat & Chem Engn, Hengyang 421002, Peoples R China.
通讯机构：
[Li Wei] H;Hengyang Normal Univ, Hengyang 421008, Peoples R China.
摘要：
A new copper coordination polymer [Cu2I(C7H5N4)(2)](n) (1) with the 3-(pyridin-2-yl)-1,2,4-triazole (Hpt) and copper iodide was synthesized. It crystallizes in the triclinic space group P (1) over bar with a = 8.6380(9), b = 9.2434(9), c = 11.8588(12) angstrom, alpha = 99.5890(10)degrees, beta = 109.0990(10)degrees, gamma = 105.2800(10)degrees, V = 829.25(15) angstrom(3), D-c = 2.180 g/cm(3), Z = 2, F(000) = 522, GOOF = 1.046, the final R= 0.0245 and wR = 0.0598. The crystal structure shows that two copper ions are bridged by two mu(2)-eta(1):eta(0) -3-(pyridin-2-y1)-1,2,4-triazole anions and two iodide ions. The coordination environments of the Cu ion are Cu(1)N-5 and Cu(2)N2I2, giving distorted square pyramidal geometry and trigon pyramid geometry. The magnetic and fluorescent properties of 1 were studied.
期刊：
Green Chemistry,2018年20(9):1970-1974 ISSN：1463-9262
通讯作者：
Liang, Yun;Liu, Jianbing
作者机构：
[Liu, Jianbing; Liang, Yun; Liu, JB; Zhu, Xiaoming; Deng, Guobo; Li, Wenguang; Luo, Xiai] Hunan Normal Univ, Key Lab Chem Biol & Tradit Chinese Med Res, Natl & Local Joint Engn Lab New Petrochem Mat & F, Minist Educ,Key Lab Assembly & Applicat Organ Fun, Changsha 410081, Hunan, Peoples R China.;[Zhu, Xiaoming] Hengyang Normal Univ, Key Lab Funct Met Organ Cpds Hunan Prov, Coll Chem & Mat Sci, Hunan Prov Univ Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Liang, Y; Liu, JB] H;Hunan Normal Univ, Key Lab Chem Biol & Tradit Chinese Med Res, Natl & Local Joint Engn Lab New Petrochem Mat & F, Minist Educ,Key Lab Assembly & Applicat Organ Fun, Changsha 410081, Hunan, Peoples R China.
摘要：
Under catalyst-free and additive-free conditions, a novel, convenient, eco-friendly method for the synthesis of benzothiazolethiones has been developed. The three-component reaction of o-iodoanilines and K2S with DMSO proceeded smoothly and the corresponding benzothiazolethiones were obtained with good isolated yields. Meanwhile, this method could be used for the synthesis of thioureas from primary diamines. Furthermore, mechanism research showed that DMSO not only functioned as a carbon source, but also as a mild oxidant in this reaction.
摘要：
A new binuclear nickel(II)complex[Ni_2(C_7N_4H_5)_3(C_9H_9O_2)]_n has been hydrothermally synthesized with nickel sulfate, 3-(pyridin-2-yl)-1H-1,2,4-triazole and 3,5-dimethylbenzoic acid (3,5-DMBA). It crystallizes in the triclinic space group P1with a = 11.5769(7), b = 12.3115(7), c = 12.6431(7)A, α = 81.4860(10)º, β = 64.2830(10)º, γ = 63.7130(10)º, V = 1453.45(15)A_3, Dc = 1.604 g/cm~3, Z = 2, F(000)= 720, the final GOOF = 1.048, R = 0.0285 and wR = 0.0628. The crystal structure shows that the whole molecule consists of two nickel ions bridged by three μ_2-η_1:η_0-3-(pyridin-2-yl)-1,2,4-triazole anions. The coordination environment of Ni(II)ion is NiO_2N_4 and NiN_5, giving a distorted octahedral geometry and square pyramidal geometry respectively. The luminescence and thermal properties of the complex were investigated.
作者：
Li Wei;Li Yu-Lin*;Li Chang-Hong*;Tan Xiong-Wen
期刊：
Chinese Journal of Structural Chemistry,2018年37(5):819-824 ISSN：0254-5861
通讯作者：
Li Yu-Lin;Li Chang-Hong
作者机构：
[Tan Xiong-Wen; Li Yu-Lin; Li Wei] Hengyang Normal Univ, Sch Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.;[Li Chang-Hong] Hunan Inst Technol, Sch Chem Engn, Hengyang 421002, Hunan, Peoples R China.;[Li Wei] Key Lab Funct Met Organ Cpds Hunan Prov Hengyang, Hengyang 421008, Hunan, Peoples R China.
通讯机构：
[Li Yu-Lin; Li Chang-Hong] H;Hengyang Normal Univ, Sch Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.;Hunan Inst Technol, Sch Chem Engn, Hengyang 421002, Hunan, Peoples R China.
关键词：
binuclear copper(II) complex;thermal stability;electrochemical and magnetic properties
摘要：
A new binuclear copper(II) complex [Cu_2(Hpt)_2(TNCA)_2(H_2O)_2]·4H_2O (1) has been synthesized with copper acetate, 5-oxo-4-oxa-tricyclo[4.2.1.0]nonane-9-carboxylic acid (TNCA) and 3-(pyridin-2-yl)-1,2,4-triazole (Hpt). It crystallizes in the triclinic space group P1, with a = 8.8199(18), b = 14.278(3), c = 15.269(3) A, α = 76.21(3)º, β = 81.07(3)º, γ = 76.07(3)º, V = 1802.7(6) A~3, D_c = 1.636 g/cm~3, Z = 2, F(000) = 916, the final GOOF = 1.051, R = 0.0556 and wR = 0.1388. The whole molecule consists of two copper ions bridged by two μ2-η1:η0-3-(pyridin-2-yl)-1,2,4-triazole anions. The coordination environment of the Cu(1) ion is CuO_2N_3, giving a distorted square pyramidal geometry. 1 exhibits antiferromagnetic interaction between Cu(II) ions, the electron transfer of 1 is irreversible in electrode reactions and the TG analysis shows that 1 is stable below 440 K.
作者：
Li Yu-Lin;Li Wei*;Li Chang-Hong*;Tan Xiong-Wen
期刊：
Chinese Journal of Structural Chemistry,2018年37(10):1651-1655 ISSN：0254-5861
通讯作者：
Li Wei;Li Chang-Hong
作者机构：
[Tan Xiong-Wen; Li Yu-Lin; Li Wei] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.;[Li Chang-Hong] Hunan Inst Technol, Dept Chem Engn, Hengyang 421002, Peoples R China.;[Li Wei] Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.
通讯机构：
[Li Wei; Li Chang-Hong] H;[Li Wei] K;Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.;Hunan Inst Technol, Dept Chem Engn, Hengyang 421002, Peoples R China.;Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.
关键词：
heteronuclear;cobalt-sodium polymer;electrochemical and fluorescent properties
摘要：
A new cobalt-sodium coordination polymer vertical bar CoNa(C9H9N3O2S)2 center dot H2O vertical bar(2)center dot C2H3N center dot H2O (1) has been synthesized with cobalt chloride, 2-(2-hydroxy-3-methoxybenzylidene)hydrazinecarbothio amide (L) and sodium hydroxide. It crystallizes in the triclinic space group P (1) over bar, with a = 9.972(4), b = 10.923(4), c = 13.489(5) angstrom, alpha = 108.005(10), beta = 92.728(10), gamma = 93.16(1)degrees, V = 1392.0(9) angstrom(3), M-r = 1151.95, D-c = 1.374 g/cm(3), Z = 2, F(000) = 592, the final GOOF = 1.126, R = 0.1091 and wR = 0.2412. Each unit molecule consists of two cobalt ions and two sodium ions bridged by four 2-(2-hydroxy-3-methoxybenzylidene)hydrazinecarbothio amide anions. The coordination environment of Co ion is CoO2N2S2, giving a distorted octahedral geometry and the Na(1) ion is NaO4N, giving a distorted square pyramidal geometry. The results show that 1 shows one strong intense fluorescence emission wavelength of 429 nm with an excitation wavelength of 376 nm, and the electron transfer of 1 is irreversible in electrode reactions.
